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Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60

Vladimir Anatol'evich Kuimov 1
Vladimir Anatol'evich Kuimov
, 
Elena Aleksandrovna Matveeva 1
Elena Aleksandrovna Matveeva
, 
Svetlana Filippovna Malysheva 1
Svetlana Filippovna Malysheva
, 
Dmitriy Olegovich Samultsev 1
Dmitriy Olegovich Samultsev
, 
Lyudmila Vasil'evna Klyba 1
Lyudmila Vasil'evna Klyba
, 
Yan V Dem'yanov 1
Yan V Dem'yanov
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2017.03.031
Published 2017-02-27
Communication , Volume 27, Issue 2, 198-200
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Kuimov V. A. et al. Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60 // Mendeleev Communications. 2017. Vol. 27. No. 2. pp. 198-200.
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Kuimov V. A., Matveeva E. A., Malysheva S. F., Samultsev D. O., Klyba L. V., Dem'yanov Y. V., Gusarova N. K., Trofimov B. A. Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60 // Mendeleev Communications. 2017. Vol. 27. No. 2. pp. 198-200.
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TY - JOUR
DO - 10.1016/j.mencom.2017.03.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.03.031
TI - Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60
T2 - Mendeleev Communications
AU - Kuimov, Vladimir Anatol'evich
AU - Matveeva, Elena Aleksandrovna
AU - Malysheva, Svetlana Filippovna
AU - Samultsev, Dmitriy Olegovich
AU - Klyba, Lyudmila Vasil'evna
AU - Dem'yanov, Yan V
AU - Gusarova, Nina Kuzminichna
AU - Trofimov, Boris Aleksandrovich
PY - 2017
DA - 2017/02/27
PB - Mendeleev Communications
SP - 198-200
IS - 2
VL - 27
ER -
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@article{2017_Kuimov,
author = {Vladimir Anatol'evich Kuimov and Elena Aleksandrovna Matveeva and Svetlana Filippovna Malysheva and Dmitriy Olegovich Samultsev and Lyudmila Vasil'evna Klyba and Yan V Dem'yanov and Nina Kuzminichna Gusarova and Boris Aleksandrovich Trofimov},
title = {Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.03.031},
number = {2},
pages = {198--200},
doi = {10.1016/j.mencom.2017.03.031}
}
MLA
Cite this
MLA Copy
Kuimov, Vladimir Anatol'evich, et al. “Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60.” Mendeleev Communications, vol. 27, no. 2, Feb. 2017, pp. 198-200. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.03.031.

Abstract

Secondary phosphines, R2PH (R = Ph, PhCH2CH2), react with fullerene C60 under microwave irradiation at 200–270°C for 1–2 h in the medium of substituted naphthalenes (1-Cl, 1-Me, 1-MeO) or without solvent to afford mono-adducts, HC60PR2, whose air oxidation gives the corresponding phosphine oxides, HC60P(O)R2, in up to 88% yield.

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