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Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction

Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
, 
Anastasiya Olegovna Sutyrina 2
Anastasiya Olegovna Sutyrina
, 
Elena Aleksandrovna Matveeva 2
Elena Aleksandrovna Matveeva
, 
Alexander Ivanovich Albanov 2
Alexander Ivanovich Albanov
, 
Lyudmila Vasil'evna Klyba 2
Lyudmila Vasil'evna Klyba
10.1016/j.mencom.2017.03.009
Published 2017-02-27
Communication , Volume 27, Issue 2, 137-138
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Artem’ev A. V. et al. Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction // Mendeleev Communications. 2017. Vol. 27. No. 2. pp. 137-138.
GOST all authors (up to 50) Copy
Artem’ev A. V., Sutyrina A. O., Matveeva E. A., Albanov A. I., Klyba L. V. Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction // Mendeleev Communications. 2017. Vol. 27. No. 2. pp. 137-138.
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TY - JOUR
DO - 10.1016/j.mencom.2017.03.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.03.009
TI - Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction
T2 - Mendeleev Communications
AU - Artem’ev, Alexandr Viktorovich
AU - Sutyrina, Anastasiya Olegovna
AU - Matveeva, Elena Aleksandrovna
AU - Albanov, Alexander Ivanovich
AU - Klyba, Lyudmila Vasil'evna
PY - 2017
DA - 2017/02/27
PB - Mendeleev Communications
SP - 137-138
IS - 2
VL - 27
ER -
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@article{2017_Artem’ev,
author = {Alexandr Viktorovich Artem’ev and Anastasiya Olegovna Sutyrina and Elena Aleksandrovna Matveeva and Alexander Ivanovich Albanov and Lyudmila Vasil'evna Klyba},
title = {Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.03.009},
number = {2},
pages = {137--138},
doi = {10.1016/j.mencom.2017.03.009}
}
MLA
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Artem’ev, Alexandr Viktorovich, et al. “Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction.” Mendeleev Communications, vol. 27, no. 2, Feb. 2017, pp. 137-138. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.03.009.

Abstract

trans,trans-1,4-Diphenylbuta-1,3-diene reacts with elemental (red) phosphorus in the superbasic KOH / DMSO (H2O) system (120°C, 3 h) to give, after acidic work-up, 1,4-diphenylbutylphosphinic acid in 48% yield.

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