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Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’

Ilya Eduardovich Nifant'ev 1, 2
Ilya Eduardovich Nifant'ev
, 
Alexey Andreevich Vinogradov 2
Alexey Andreevich Vinogradov
, 
Alexander Andreevich Vinogradov 2
Alexander Andreevich Vinogradov
, 
Stanislav Igorevich Bezzubov 3
Stanislav Igorevich Bezzubov
, 
Pavel Vasil'evich Ivchenko 1, 2
Pavel Vasil'evich Ivchenko
10.1016/j.mencom.2017.01.010
Published 2016-12-29
Communication , Volume 27, Issue 1, 35-37
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Nifant'ev I. E. et al. Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’ // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 35-37.
GOST all authors (up to 50) Copy
Nifant'ev I. E., Vinogradov A. A., Vinogradov A. A., Bezzubov S. I., Ivchenko P. V. Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’ // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 35-37.
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TY - JOUR
DO - 10.1016/j.mencom.2017.01.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.010
TI - Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’
T2 - Mendeleev Communications
AU - Nifant'ev, Ilya Eduardovich
AU - Vinogradov, Alexey Andreevich
AU - Vinogradov, Alexander Andreevich
AU - Bezzubov, Stanislav Igorevich
AU - Ivchenko, Pavel Vasil'evich
PY - 2016
DA - 2016/12/29
PB - Mendeleev Communications
SP - 35-37
IS - 1
VL - 27
ER -
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@article{2016_Nifant'ev,
author = {Ilya Eduardovich Nifant'ev and Alexey Andreevich Vinogradov and Alexander Andreevich Vinogradov and Stanislav Igorevich Bezzubov and Pavel Vasil'evich Ivchenko},
title = {Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’},
journal = {Mendeleev Communications},
year = {2016},
volume = {27},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.010},
number = {1},
pages = {35--37},
doi = {10.1016/j.mencom.2017.01.010}
}
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Nifant'ev, Ilya Eduardovich, et al. “Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’.” Mendeleev Communications, vol. 27, no. 1, Dec. 2016, pp. 35-37. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.010.

Abstract

Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.

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