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Trifluoroacetyl nitrate

Victor Petrovich Zelenov 1
Victor Petrovich Zelenov
, 
Sergei Sergeevich Bukalov 2
Sergei Sergeevich Bukalov
, 
Larisa Aleksandrovna Leites 2
Larisa Aleksandrovna Leites
, 
Rinat Ravil'evich Aysin 2
Rinat Ravil'evich Aysin
, 
Alexandr Nikolaevich Subbotin 1
Alexandr Nikolaevich Subbotin
, 
Marina Ivanovna Struchkova 1
Marina Ivanovna Struchkova
, 
10.1016/j.mencom.2017.01.009
Published 2016-12-29
Communication , Volume 27, Issue 1, 31-34
13
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Zelenov V. P. et al. Trifluoroacetyl nitrate // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 31-34.
GOST all authors (up to 50) Copy
Zelenov V. P., Bukalov S. S., Leites L. A., Aysin R. R., Subbotin A. N., Struchkova M. I., Fedyanin I. V. Trifluoroacetyl nitrate // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 31-34.
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TY - JOUR
DO - 10.1016/j.mencom.2017.01.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.009
TI - Trifluoroacetyl nitrate
T2 - Mendeleev Communications
AU - Zelenov, Victor Petrovich
AU - Bukalov, Sergei Sergeevich
AU - Leites, Larisa Aleksandrovna
AU - Aysin, Rinat Ravil'evich
AU - Subbotin, Alexandr Nikolaevich
AU - Struchkova, Marina Ivanovna
AU - Fedyanin, Ivan Vladimirovich
PY - 2016
DA - 2016/12/29
PB - Mendeleev Communications
SP - 31-34
IS - 1
VL - 27
ER -
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@article{2016_Zelenov,
author = {Victor Petrovich Zelenov and Sergei Sergeevich Bukalov and Larisa Aleksandrovna Leites and Rinat Ravil'evich Aysin and Alexandr Nikolaevich Subbotin and Marina Ivanovna Struchkova and Ivan Vladimirovich Fedyanin},
title = {Trifluoroacetyl nitrate},
journal = {Mendeleev Communications},
year = {2016},
volume = {27},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.009},
number = {1},
pages = {31--34},
doi = {10.1016/j.mencom.2017.01.009}
}
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Cite this
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Zelenov, Victor Petrovich, et al. “Trifluoroacetyl nitrate.” Mendeleev Communications, vol. 27, no. 1, Dec. 2016, pp. 31-34. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.009.

Abstract

Individual trifluoroacetyl nitrate (TFAN) was synthesized by the reaction of N2O5 with trifluoroacetic anhydride (TFAA) and was characterized by 13C, 14N, 15N, and 19F NMR and Raman spectroscopy. In the gas phase TFAN partially decomposes into N2O5 and TFAA, and in solutions the equilibrium is shifted to TFAN. Mono nitration of [2.2]paracyclophane with TFAN proceeds in good yields.

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