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1-Alkyl-2-(Z-1,2-diferrocenylvinyl)oxazolinium tetrafluoroborates: synthesis, characterization and nucleophilic ring opening

J J Sanchez Garcia 1
J J Sanchez Garcia
, 
Marcos Flores-Alamo 1
Marcos Flores-Alamo
, 
Denis E Chirinos Flores 1
Denis E Chirinos Flores
, 
Elena Ivanovna Klimova 1
Elena Ivanovna Klimova
10.1016/j.mencom.2017.01.007
Published 2016-12-29
Communication , Volume 27, Issue 1, 26-28
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Sanchez Garcia J. J. et al. 1-Alkyl-2-(Z-1,2-diferrocenylvinyl)oxazolinium tetrafluoroborates: synthesis, characterization and nucleophilic ring opening // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 26-28.
GOST all authors (up to 50) Copy
Sanchez Garcia J. J., Flores-Alamo M., Chirinos Flores D. E., Klimova E. I. 1-Alkyl-2-(Z-1,2-diferrocenylvinyl)oxazolinium tetrafluoroborates: synthesis, characterization and nucleophilic ring opening // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 26-28.
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TY - JOUR
DO - 10.1016/j.mencom.2017.01.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.007
TI - 1-Alkyl-2-(Z-1,2-diferrocenylvinyl)oxazolinium tetrafluoroborates: synthesis, characterization and nucleophilic ring opening
T2 - Mendeleev Communications
AU - Sanchez Garcia, J J
AU - Flores-Alamo, Marcos
AU - Chirinos Flores, Denis E
AU - Klimova, Elena Ivanovna
PY - 2016
DA - 2016/12/29
PB - Mendeleev Communications
SP - 26-28
IS - 1
VL - 27
ER -
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@article{2016_Sanchez Garcia,
author = {J J Sanchez Garcia and Marcos Flores-Alamo and Denis E Chirinos Flores and Elena Ivanovna Klimova},
title = {1-Alkyl-2-(Z-1,2-diferrocenylvinyl)oxazolinium tetrafluoroborates: synthesis, characterization and nucleophilic ring opening},
journal = {Mendeleev Communications},
year = {2016},
volume = {27},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.007},
number = {1},
pages = {26--28},
doi = {10.1016/j.mencom.2017.01.007}
}
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Sanchez Garcia, J. J., et al. “1-Alkyl-2-(Z-1,2-diferrocenylvinyl)oxazolinium tetrafluoroborates: synthesis, characterization and nucleophilic ring opening.” Mendeleev Communications, vol. 27, no. 1, Dec. 2016, pp. 26-28. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.007.

Abstract

2,3-Diferrocenyl-1-ethoxycyclopropenylium tetrafluoroborate on reaction with 2-(alkylamino)ethanols at ∼80–82°C in the presence of triethylamine gives mixtures of novel 2-(1,2-diferrocenylvinyl) oxazolinium salts and 3,6-diaza-(E-2,3-diferrocenyl) acryloyl-3,6-dialkylheptanols. The oxazolidinium salts undergo heterocyclic ring-opening in the presence of N-nucleophiles to afford 2,3-diferrocenylacrylamide derivatives.

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