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3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals

Yulia Mikhailovna Volkova 1
Yulia Mikhailovna Volkova
, 
Alexander Yur'evich Makarov 1
Alexander Yur'evich Makarov
, 
Samat Baurzhanovich Zikirin 2, 3
Samat Baurzhanovich Zikirin
, 
Alexander Mikhailovich Genaev 1
Alexander Mikhailovich Genaev
, 
Irina Yur'evna Bagryanskaya 1, 4
Irina Yur'evna Bagryanskaya
, 
Andrey Viktorovich Zibarev 1, 5
Andrey Viktorovich Zibarev
10.1016/j.mencom.2017.01.005
Published 2016-12-29
Communication , Volume 27, Issue 1, 19-22
16
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Volkova Y. M. et al. 3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 19-22.
GOST all authors (up to 50) Copy
Volkova Y. M., Makarov A. Y., Zikirin S. B., Genaev A. M., Bagryanskaya I. Y., Zibarev A. V. 3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals // Mendeleev Communications. 2016. Vol. 27. No. 1. pp. 19-22.
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TY - JOUR
DO - 10.1016/j.mencom.2017.01.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.005
TI - 3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals
T2 - Mendeleev Communications
AU - Volkova, Yulia Mikhailovna
AU - Makarov, Alexander Yur'evich
AU - Zikirin, Samat Baurzhanovich
AU - Genaev, Alexander Mikhailovich
AU - Bagryanskaya, Irina Yur'evna
AU - Zibarev, Andrey Viktorovich
PY - 2016
DA - 2016/12/29
PB - Mendeleev Communications
SP - 19-22
IS - 1
VL - 27
ER -
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@article{2016_Volkova,
author = {Yulia Mikhailovna Volkova and Alexander Yur'evich Makarov and Samat Baurzhanovich Zikirin and Alexander Mikhailovich Genaev and Irina Yur'evna Bagryanskaya and Andrey Viktorovich Zibarev},
title = {3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals},
journal = {Mendeleev Communications},
year = {2016},
volume = {27},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.005},
number = {1},
pages = {19--22},
doi = {10.1016/j.mencom.2017.01.005}
}
MLA
Cite this
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Volkova, Yulia Mikhailovna, et al. “3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals.” Mendeleev Communications, vol. 27, no. 1, Dec. 2016, pp. 19-22. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.01.005.

Abstract

The archetypal 3,1,2,4-benzothiaselenadiazine, its 5- and 8-Me3Si derivatives and related dithiadiazine and trithiadiazepine were synthesized from 2-Me3SiC6H4N=S=NSiMe3 by the action of SeCl2, SeCl4, SCl2, and S2Cl2 and converted into persistent 2,1,3-benzothiaselenazolyl and 1,2,3-benzodithiazolyl radicals characterized by EPR spectroscopy and DFT calculations.

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