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Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium

Alexander Victorovich Babkin 1
Alexander Victorovich Babkin
, 
Andrey Fedorovich Asachenko 2
Andrey Fedorovich Asachenko
, 
Dmitry Vadimovich Uborsky 1
Dmitry Vadimovich Uborsky
, 
Dmitry Sergeyevich Kononovich 1
Dmitry Sergeyevich Kononovich
, 
Vyacheslav Valeryevich Izmer 1
Vyacheslav Valeryevich Izmer
, 
Vera Andreevna Kudakina 1
Vera Andreevna Kudakina
, 
Viktoria Aleksandrovna Shnaider 1
Viktoria Aleksandrovna Shnaider
, 
Nikolaj Evgenievich Shevchenko 1
Nikolaj Evgenievich Shevchenko
, 
Alexander Zel'manovich Voskoboynikov 1
Alexander Zel'manovich Voskoboynikov
10.1016/j.mencom.2016.11.033
Published 2016-10-27
Communication , Volume 26, Issue 6, 555-557
3
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Babkin A. V. et al. Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 555-557.
GOST all authors (up to 50) Copy
Babkin A. V., Asachenko A. F., Uborsky D. V., Kononovich D. S., Izmer V. V., Kudakina V. A., Shnaider V. A., Shevchenko N. E., Voskoboynikov A. Z. Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 555-557.
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TY - JOUR
DO - 10.1016/j.mencom.2016.11.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.033
TI - Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium
T2 - Mendeleev Communications
AU - Babkin, Alexander Victorovich
AU - Asachenko, Andrey Fedorovich
AU - Uborsky, Dmitry Vadimovich
AU - Kononovich, Dmitry Sergeyevich
AU - Izmer, Vyacheslav Valeryevich
AU - Kudakina, Vera Andreevna
AU - Shnaider, Viktoria Aleksandrovna
AU - Shevchenko, Nikolaj Evgenievich
AU - Voskoboynikov, Alexander Zel'manovich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 555-557
IS - 6
VL - 26
ER -
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@article{2016_Babkin,
author = {Alexander Victorovich Babkin and Andrey Fedorovich Asachenko and Dmitry Vadimovich Uborsky and Dmitry Sergeyevich Kononovich and Vyacheslav Valeryevich Izmer and Vera Andreevna Kudakina and Viktoria Aleksandrovna Shnaider and Nikolaj Evgenievich Shevchenko and Alexander Zel'manovich Voskoboynikov},
title = {Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.033},
number = {6},
pages = {555--557},
doi = {10.1016/j.mencom.2016.11.033}
}
MLA
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MLA Copy
Babkin, Alexander Victorovich, et al. “Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 555-557. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.033.

Abstract

A novel protocol for efficient coupling of nitrobenzene and aniline in poly(ethylene glycol) medium in the presence of KOH giving diphenylamine derivatives has been developed, to enable the exclusion of the toxic tetramethylammonium hydroxide catalyst commonly used in the rubber antidegradant industry.

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