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New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde

Maxim Vyacheslavovich Arsenyev 1
Maxim Vyacheslavovich Arsenyev
, 
Eugeny Vladimirovich Baranov 2
Eugeny Vladimirovich Baranov
, 
Margarita Petrovna Shurygina 2
Margarita Petrovna Shurygina
, 
Sergey Arturovich Chesnokov 2
Sergey Arturovich Chesnokov
, 
Gleb Arsent'evich Abakumov 2
Gleb Arsent'evich Abakumov
10.1016/j.mencom.2016.11.032
Published 2016-10-27
Communication , Volume 26, Issue 6, 552-554
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Arsenyev M. V. et al. New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 552-554.
GOST all authors (up to 50) Copy
Arsenyev M. V., Baranov E. V., Shurygina M. P., Chesnokov S. A., Abakumov G. A. New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 552-554.
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TY - JOUR
DO - 10.1016/j.mencom.2016.11.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.032
TI - New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde
T2 - Mendeleev Communications
AU - Arsenyev, Maxim Vyacheslavovich
AU - Baranov, Eugeny Vladimirovich
AU - Shurygina, Margarita Petrovna
AU - Chesnokov, Sergey Arturovich
AU - Abakumov, Gleb Arsent'evich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 552-554
IS - 6
VL - 26
ER -
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@article{2016_Arsenyev,
author = {Maxim Vyacheslavovich Arsenyev and Eugeny Vladimirovich Baranov and Margarita Petrovna Shurygina and Sergey Arturovich Chesnokov and Gleb Arsent'evich Abakumov},
title = {New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.032},
number = {6},
pages = {552--554},
doi = {10.1016/j.mencom.2016.11.032}
}
MLA
Cite this
MLA Copy
Arsenyev, Maxim Vyacheslavovich, et al. “New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 552-554. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.032.

Abstract

Reduction of aldehyde group in 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde leads to methoxymethyl (NaBH4, MeOH) or methyl (Zn, MeOH) analogues, which were further oxidized into the corresponding o-benzoquinones. Their photostability in benzene increases substantially on replacement of the 6-positioned Me substituent with the CH2OMe group.

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