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Synthesis and polymerization of disiloxane Si–O–Si-linked phthalonitrile monomer

Pavel Borisovich Dzhevakov 1
Pavel Borisovich Dzhevakov
, 
Roman Fedorovich Korotkov 2
Roman Fedorovich Korotkov
, 
Boris A. Bulgakov 1, 3
Boris A. Bulgakov
, 
Alexander Victorovich Babkin 1, 3
Alexander Victorovich Babkin
, 
Alexey Valer'evich Kepman 1, 3
Alexey Valer'evich Kepman
, 
Viktor Vasilyvich Avdeev 3
Viktor Vasilyvich Avdeev
10.1016/j.mencom.2016.11.023
Published 2016-10-27
Communication , Volume 26, Issue 6, 527-529
32
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Dzhevakov P. B. et al. Synthesis and polymerization of disiloxane Si–O–Si-linked phthalonitrile monomer // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 527-529.
GOST all authors (up to 50) Copy
Dzhevakov P. B., Korotkov R. F., Bulgakov B. A., Babkin A. V., Kepman A. V., Avdeev V. V. Synthesis and polymerization of disiloxane Si–O–Si-linked phthalonitrile monomer // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 527-529.
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TY - JOUR
DO - 10.1016/j.mencom.2016.11.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.023
TI - Synthesis and polymerization of disiloxane Si–O–Si-linked phthalonitrile monomer
T2 - Mendeleev Communications
AU - Dzhevakov, Pavel Borisovich
AU - Korotkov, Roman Fedorovich
AU - Bulgakov, Boris A.
AU - Babkin, Alexander Victorovich
AU - Kepman, Alexey Valer'evich
AU - Avdeev, Viktor Vasilyvich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 527-529
IS - 6
VL - 26
ER -
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@article{2016_Dzhevakov,
author = {Pavel Borisovich Dzhevakov and Roman Fedorovich Korotkov and Boris A. Bulgakov and Alexander Victorovich Babkin and Alexey Valer'evich Kepman and Viktor Vasilyvich Avdeev},
title = {Synthesis and polymerization of disiloxane Si–O–Si-linked phthalonitrile monomer},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.023},
number = {6},
pages = {527--529},
doi = {10.1016/j.mencom.2016.11.023}
}
MLA
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Dzhevakov, Pavel Borisovich, et al. “Synthesis and polymerization of disiloxane Si–O–Si-linked phthalonitrile monomer.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 527-529. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.023.

Abstract

A novel low melting highly hydrolytically stable phthalonitrile monomer containing Ar–Si–O–Si–Ar bonds with Tg = 4°C exhibits good rheological properties. Its cured resin possesses high heat deflection temperature (Thd = 471°C) and demonstrates high thermal and thermooxidative stabilities (T5% = 503°C, TOS5% = 495°C, Yc = 76%) that are typical of phthalonitrile matrices.

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