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HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents

Dmitry Sergeyevich Ryabukhin 1, 2
Dmitry Sergeyevich Ryabukhin
, 
Aleksandr Viktorovich Vasilyev 1, 2
Aleksandr Viktorovich Vasilyev
10.1016/j.mencom.2016.11.013
Published 2016-10-27
Communication , Volume 26, Issue 6, 500-501
6
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Ryabukhin D. S., Vasilyev A. V. HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 500-501.
GOST all authors (up to 50) Copy
Ryabukhin D. S., Vasilyev A. V. HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 500-501.
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TY - JOUR
DO - 10.1016/j.mencom.2016.11.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.013
TI - HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents
T2 - Mendeleev Communications
AU - Ryabukhin, Dmitry Sergeyevich
AU - Vasilyev, Aleksandr Viktorovich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 500-501
IS - 6
VL - 26
ER -
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@article{2016_Ryabukhin,
author = {Dmitry Sergeyevich Ryabukhin and Aleksandr Viktorovich Vasilyev},
title = {HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.013},
number = {6},
pages = {500--501},
doi = {10.1016/j.mencom.2016.11.013}
}
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Ryabukhin, Dmitry Sergeyevich, and Aleksandr Viktorovich Vasilyev. “HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 500-501. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.013.

Abstract

Arylacetylenes, conjugated with electron-withdrawing groups, ArC≡C(EWG) [EWG = SO2Ph, PO(OEt)2, COMe, CO2Me] in reaction with benzene at room temperature or 130°C (glass high pressure tube) for 1–10h under the action of acidic zeolite HUSY (Si /Al ratio is 15) afford products of hydrophenylation of acetylene bond Ar(Ph)C=CH(EWG) in yields of 56–98%.

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