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Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst

Alexander Avraamovich Greish 1
Alexander Avraamovich Greish
, 
Elena Dmitrievna Finashina 1
Elena Dmitrievna Finashina
, 
Olga P. Tkachenko 1
Olga P. Tkachenko
, 
Elena Vladimirovna Shuvalova 1
Elena Vladimirovna Shuvalova
, 
10.1016/j.mencom.2016.11.012
Published 2016-10-27
Communication , Volume 26, Issue 6, 497-499
12
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Greish A. A. et al. Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 497-499.
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Greish A. A., Finashina E. D., Tkachenko O. P., Shuvalova E. V., Kustov L. M. Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 497-499.
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TY - JOUR
DO - 10.1016/j.mencom.2016.11.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.012
TI - Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst
T2 - Mendeleev Communications
AU - Greish, Alexander Avraamovich
AU - Finashina, Elena Dmitrievna
AU - Tkachenko, Olga P.
AU - Shuvalova, Elena Vladimirovna
AU - Kustov, Leonid Modestovich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 497-499
IS - 6
VL - 26
ER -
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@article{2016_Greish,
author = {Alexander Avraamovich Greish and Elena Dmitrievna Finashina and Olga P. Tkachenko and Elena Vladimirovna Shuvalova and Leonid Modestovich Kustov},
title = {Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.012},
number = {6},
pages = {497--499},
doi = {10.1016/j.mencom.2016.11.012}
}
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Greish, Alexander Avraamovich, et al. “Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 497-499. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.012.

Abstract

The SnO2 /Al2O3 catalyst promoted with CuCl2, ZnCl2, KF exhibited high activity in the synthesis of dimethyl carbonate from methanol and CO2 (130°C, 16bar, 4h) providing the 17.8% yield of the product with ca. 99% selectivity.

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