Home / Publications / Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes

Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes

, 
Galina Olegovna Bragina 1
Galina Olegovna Bragina
, 
Alexander Viktorovich Rassolov 1
Alexander Viktorovich Rassolov
,  , 
Galina Nikolaevna Baeva 1
Galina Nikolaevna Baeva
, 
Olga P. Tkachenko 1
Olga P. Tkachenko
, 
Ilya Arkad'evich Yakushev 2
Ilya Arkad'evich Yakushev
, 
Michael Natanovich Vargaftik 2
Michael Natanovich Vargaftik
, 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
10.1016/j.mencom.2016.11.011
Published 2016-10-27
Communication , Volume 26, Issue 6, 494-496
29
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Markov P. V. et al. Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 494-496.
GOST all authors (up to 50) Copy
Markov P. V., Bragina G. O., Rassolov A. V., Mashkovsky I. S., Baeva G. N., Tkachenko O. P., Yakushev I. A., Vargaftik M. N., Stakheev A. Y. Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 494-496.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2016.11.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.011
TI - Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes
T2 - Mendeleev Communications
AU - Markov, Pavel Viktorovich
AU - Bragina, Galina Olegovna
AU - Rassolov, Alexander Viktorovich
AU - Mashkovsky, Igor' Sergeevich
AU - Baeva, Galina Nikolaevna
AU - Tkachenko, Olga P.
AU - Yakushev, Ilya Arkad'evich
AU - Vargaftik, Michael Natanovich
AU - Stakheev, Aleksandr Yurevich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 494-496
IS - 6
VL - 26
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Markov,
author = {Pavel Viktorovich Markov and Galina Olegovna Bragina and Alexander Viktorovich Rassolov and Igor' Sergeevich Mashkovsky and Galina Nikolaevna Baeva and Olga P. Tkachenko and Ilya Arkad'evich Yakushev and Michael Natanovich Vargaftik and Aleksandr Yurevich Stakheev},
title = {Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.011},
number = {6},
pages = {494--496},
doi = {10.1016/j.mencom.2016.11.011}
}
MLA
Cite this
MLA Copy
Markov, Pavel Viktorovich, et al. “Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 494-496. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.011.

Abstract

The 1% Pd–1% In / MgAl2O4 catalyst demonstrated excellent selectivity in the semi-hydrogenation of internal 1-phenylprop-1-yne, which exceeded the selectivity of a commercial Lindlar catalyst and reference monometallic 0.5% Pd/MgAl2O4 catalyst due to Pd–In alloy formation.

References

1.
10.1016/j.mencom.2016.11.011_bib0005
Blaser
Weinheim, 2008
2.
Development of new methods in modern selective organic synthesis: Preparation of functionalized molecules with atomic precision
Ananikov V.P., Khemchyan L.L., Ivanova Y.V., Bukhtiyarov V.I., Sorokin A.M., Prosvirin I.P., Vatsadze S.Z., Medved'ko A.V., Nuriev V.N., Dilman A.D., Levin V.V., Koptyug I.V., Kovtunov K.V., Zhivonitko V.V., Likholobov V.A., et. al.
Russian Chemical Reviews, 2014
3.
Ananikov V.P., Khokhlova E.A., Egorov M.P., Sakharov A.M., Zlotin S.G., Kucherov A.V., Kustov L.M., Gening M.L., Nifantiev N.E.
Mendeleev Communications, 2015
4.
10.1016/j.mencom.2016.11.011_bib0020
Nishimura
Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis, 2001
5.
New high-selectivity hydrogenation catalysts prepared from bimetallic acetate complexes
Mashkovskii I.S., Tkachenko O.P., Baeva G.N., Stakheev A.Y.
Kinetics and Catalysis, 2009
6.
Mashkovsky I.S., Baeva G.N., Stakheev A.Y., Vargaftik M.N., Kozitsyna N.Y., Moiseev I.I.
Mendeleev Communications, 2014
7.
Acetylene and Ethylene Hydrogenation on Alumina Supported Pd-Ag Model Catalysts
Khan N.A., Shaikhutdinov S., Freund H.-.
Catalysis Letters, 2006
8.
Changes in the course of reaction and regeneration of a Pd-Ag/Al2O3 catalyst for the selective hydrogenation of acetylene
Lamberov A.A., Egorova S.R., Il’yasov I.R., Gil’manov K.K., Trifonov S.V., Shatilov V.M., Ziyatdinov A.S.
Kinetics and Catalysis, 2007
10.
Pd-Cu catalysts from acetate complexes in liquid-phase diphenylacetylene hydrogenation
Markov P.V., Bragina G.O., Baeva G.N., Tkachenko O.P., Mashkovsky I.S., Yakushev I.A., Kozitsyna N.Y., Vargaftik M.N., Stakheev A.Y.
Kinetics and Catalysis, 2015
11.
10.1016/j.mencom.2016.11.011_bib0055
Mashkovsky
Izv. Akad. Nauk, Ser. Khim., 2016
12.
EXAFS study of Pd/Sibunit and Pd–Ga/Sibunit catalysts for liquid-phase hydrogenation of acetylene to ethylene
Smirnova N.S., Shlyapin D.A., Shitova N.B., Kochubey D.I., Tsyrul’nikov P.G.
Journal of Molecular Catalysis A Chemical, 2015
13.
Surface dynamics of the intermetallic catalyst Pd2Ga, Part I – Structural stability in UHV and different gas atmospheres
Wowsnick G., Teschner D., Kasatkin I., Girgsdies F., Armbrüster M., Zhang A., Grin Y., Schlögl R., Behrens M.
Journal of Catalysis, 2014
14.
Surface dynamics of the intermetallic catalyst Pd2Ga, Part II – Reactivity and stability in liquid-phase hydrogenation of phenylacetylene
Wowsnick G., Teschner D., Armbrüster M., Kasatkin I., Girgsdies F., Grin Y., Schlögl R., Behrens M.
Journal of Catalysis, 2014
15.
Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart I: Preparation and structural investigation under reaction conditions
OSSWALD J., GIEDIGKEIT R., JENTOFT R., ARMBRUSTER M., GIRGSDIES F., KOVNIR K., RESSLER T., GRIN Y., SCHLOGL R.
Journal of Catalysis, 2008
16.
Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart II: Surface characterization and catalytic performance
OSSWALD J., KOVNIR K., ARMBRUSTER M., GIEDIGKEIT R., JENTOFT R., WILD U., GRIN Y., SCHLOGL R.
Journal of Catalysis, 2008
19.
10.1016/j.mencom.2016.11.011_bib0085
Smirnova
Chem. Sustain. Develop., 2013
20.
Pt,In and Pd,In catalysts for the hydrogenation of nitrates and nitrites in water. FTIR characterization and reaction studies
Marchesini F.A., Gutierrez L.B., Querini C.A., Miró E.E.
Chemical Engineering Journal, 2010
21.
I. A. Yakushev, PhD Thesis, Moscow, 2015.
22.
10.1016/j.mencom.2016.11.011_bib0100
Turova
Proceedings of the II All-Russian Congress on Catalysis ‘Roscatalysis’, 2014
24.
10.1016/j.mencom.2016.11.011_bib0110
Davydov
Molecular Spectroscopy of Oxide Catalyst Surfaces, 2003
26.
10.1016/j.mencom.2016.11.011_bib0120
Bond
Metal-Catalysed Reactions of Hydrocarbons, 2005