Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes

Chamkin, Alexander Andreevich; Finogenova, Anastasiia Mikhailovna; Nelyubina, Yulia Vladimirovna; Laskova, Julia Nikolaevna; Kudinov, Alexander Rudolfovich; Loginov, Dmitry Alexandrovich

doi:10.1016/j.mencom.2016.11.010

Home / Publications / Iodide [(η⁵-indenyl)IrI₂]_n: an effective precursor to (indenyl)iridium sandwich complexes

Iodide [(η⁵-indenyl)IrI₂]_n: an effective precursor to (indenyl)iridium sandwich complexes

Alexander Andreevich Chamkin ¹

Alexander Andreevich Chamkin

,

Anastasiia Mikhailovna Finogenova ¹

Anastasiia Mikhailovna Finogenova

,

Yulia Vladimirovna Nelyubina ¹

Yulia Vladimirovna Nelyubina

0000-0002-9121-0040

,

Julia Nikolaevna Laskova ¹

Julia Nikolaevna Laskova

,

Alexander Rudolfovich Kudinov ¹

Alexander Rudolfovich Kudinov

,

Dmitry Alexandrovich Loginov ¹

Dmitry Alexandrovich Loginov

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2016.11.010

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Published 2016-10-27

Communication , Volume 26, Issue 6, 491-493

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Chamkin A. A. et al. Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 491-493.

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Chamkin A. A., Finogenova A. M., Nelyubina Y. V., Laskova J. N., Kudinov A. R., Loginov D. A. Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 491-493.

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TY - JOUR

DO - 10.1016/j.mencom.2016.11.010

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.010

TI - Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes

T2 - Mendeleev Communications

AU - Chamkin, Alexander Andreevich

AU - Finogenova, Anastasiia Mikhailovna

AU - Nelyubina, Yulia Vladimirovna

AU - Laskova, Julia Nikolaevna

AU - Kudinov, Alexander Rudolfovich

AU - Loginov, Dmitry Alexandrovich

PY - 2016

DA - 2016/10/27

PB - Mendeleev Communications

SP - 491-493

IS - 6

VL - 26

ER -

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@article{2016_Chamkin,

author = {Alexander Andreevich Chamkin and Anastasiia Mikhailovna Finogenova and Yulia Vladimirovna Nelyubina and Julia Nikolaevna Laskova and Alexander Rudolfovich Kudinov and Dmitry Alexandrovich Loginov},

title = {Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes},

journal = {Mendeleev Communications},

year = {2016},

volume = {26},

publisher = {Mendeleev Communications},

month = {Oct},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.010},

number = {6},

pages = {491--493},

doi = {10.1016/j.mencom.2016.11.010}

}

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Chamkin, Alexander Andreevich, et al. “Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 491-493. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.010.

Abstract

The reactions of [(η⁵-indenyl)IrI₂]_η with CpTl or arenes in the presence of AgBF₄ afford [(η⁵-indenyl)IrCp]⁺ or [(η⁵-indenyl)Ir(arene)]²⁺ cations (arene = benzene, mesitylene, durene or hexamethylbenzene); the structures of (η⁵-indenyl)-Ir(C₂H₄)₂ and [(η⁵-indenyl)IrCp]PF₆ were characterized by X-ray diffraction analysis.

References

1.

10.1039/c2cs15281a

C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation.

Song G., Wang F., Li X.

Chemical Society Reviews, 2012

2.

10.1016/j.mencom.2016.11.010_sbref0005b

Patureau

Aldrichimica Acta, 2012

3.

10.1055/s-0034-1379890

Transition-Metal-Catalyzed Direct C–H Functionalization under External-Oxidant-Free Conditions

Cui X., Mo J., Wang L., Liu Y.

Synthesis, 2015

4.

10.1039/C5CC00497G

C–H bond functionalization based on metal carbene migratory insertion

Hu F., Xia Y., Ma C., Zhang Y., Wang J.

Chemical Communications, 2015

5.

10.1021/jo7022087

Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C−H and C−C Bond Cleavages

Uto T., Shimizu M., Ueura K., Tsurugi H., Satoh T., Miura M.

Journal of Organic Chemistry, 2007

6.

10.1039/DT9770001654

Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part XII. Tris(solvent) complexes and complexes of η⁶-benzene, -naphthalene, -phenanthrene, -indene, -indole, and -fluorene and η⁵-lndenyl and -indolyl

White C., Thompson S.J., Maitlis P.M.

Journal of the Chemical Society Dalton Transactions, 1977

7.

10.1039/DT9800001048

Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 26. Dicationic η⁵-aniline and η⁶-anisole complexes

Espinet P., Bailey P.M., Downey R.F., Maitlis P.M.

Journal of the Chemical Society Dalton Transactions, 1980

8.

10.1016/0022-328X(84)80470-2

Double nucleophilic attack on η6-arene(pentamethylcyclopentadienyl)iridium dications. Routes from substituted benzenes to substituted cyclohexenes by addition of two hydrides and two protons

Grundy S.L., Maitlis P.M.

Journal of Organometallic Chemistry, 1984

9.

10.1016/j.mencom.2016.11.010_sbref0010d

Fontaine

J. Chem. Soc., Dalton Trans., 1990

10.

10.1021/om00034a041

Triple-decker complexes. 9. Triple-decker complexes with bridging cyclopentadienyl ligands and novel cyclopentadienyl transfer reactions

Herberich G.E., Englert U., Marken F., Hofmann P.

Organometallics, 1993

11.

10.1016/S0022-328X(02)01109-9

Dicationic triple-decker complexes with a bridging boratabenzene ligand

Kudinov A.R., Loginov D.A., Starikova Z.A., Petrovskii P.V.

Journal of Organometallic Chemistry, 2002

12.

10.1007/s11172-005-0054-5

Arene complexes [(η-C5H5)M(η-C6R6)]2+ (M = Rh, Ir)

Loginov D.A., Vinogradov M.M., Starikova Z.A., Petrovskii P.V., Kudinov A.R.

Russian Chemical Bulletin, 2004

13.

10.1002/ejic.200400915

Reactions of the B‐Phenylborole Complex [CpRh(η⁵‐C₄H₄BPh)] with Metalloelectrophiles [(ring)M]²⁺

Loginov D.A., Muratov D.V., Petrovskii P.V., Starikova Z.A., Corsini M., Laschi F., de Biani Fabrizi F., Zanello P., Kudinov A.R.

European Journal of Inorganic Chemistry, 2005

14.

10.1007/s11172-006-0457-y

Stacking reactions of the borole complex Cp*Rh(η5-C4H4BPh) with the dicationic fragments [Cp*M]2+ (M = Rh or Ir)

Loginov D.A., Muratov D.V., Starikova Z.A., Petrovskii P.V., Kudinov A.R.

Russian Chemical Bulletin, 2006

15.

10.1016/j.jorganchem.2006.05.014

The first metallacarborane triple-decker complexes with a bridging borole ligand

Loginov D.A., Muratov D.V., Starikova Z.A., Petrovskii P.V., Kudinov A.R.

Journal of Organometallic Chemistry, 2006

16.

10.1016/j.jorganchem.2012.12.021

(Cyclopentadienyl)metalladicarbollides 3-(η-C5R5)-3,1,2-MC2B9H11 (M = Co, Rh, Ir): Synthesis, electrochemistry, and bonding

Loginov D.A., Starikova Z.A., Corsini M., Zanello P., Kudinov A.R.

Journal of Organometallic Chemistry, 2013

17.

10.1021/om00041a013

Synthesis and carbon-hydrogen activation reactions of .eta.5-indenyl(trimethylphosphine)iridium alkyl and hydride complexes

Foo T., Bergman R.G.

Organometallics, 1992

18.

10.1002/9780470132456.ch18

Chlorobis(cyclooctene)rhodium(I) and -Iridium(I) Complexes

van der Ent A., Onderdelinden A.L., Schunn R.A.

Inorganic Syntheses, 1973

19.

10.1016/j.mencom.2012.06.006

Reactions of the (cyclooctadiene)iridium complex CpIr(cod) with halogens

Loginov D.A., Miloserdov A.M., Starikova Z.A., Petrovskii P.V., Kudinov A.R.

Mendeleev Communications, 2012

20.

10.1016/j.mencom.2016.11.010_bib0035

Merola

Acta Crystallogr, 2013

21.

10.1021/om00124a022

Control of slippage and conformation in indenyl complexes

Faller J.W., Crabtree R.H., Habib A.

Organometallics, 1985

22.

10.1016/0022-328X(90)87268-I

Flexible coordination of indenyl ligands in sandwich complexes of transition metals. Molecular structures of [(η-C9R7)2M] (M = Fe, R = H, Me; M = Co, Ni, R = H): Direct measurement of the degree of slip-fold distortion as a function of d-electron count

Westcott S.A., Kakkar A.K., Stringer G., Taylor N.J., Marder T.B.

Journal of Organometallic Chemistry, 1990

23.

10.1021/om9706065

Heterobimetallic Indenyl Complexes. Synthesis and Carbonylation Reaction of anti-[Cr(CO)₃-μ,η:η-indenyl-Ir(COD)]

Cecchetto P., Ceccon A., Gambaro A., Santi S., Ganis P., Gobetto R., Valle G., Venzo A.

Organometallics, 1998

24.

10.1021/om970579i

Synthesis and Reactivity of Ir(CO)(η²-C₂R₂)(η⁵-C₉H₇) (R = Ph, Tol). Alkyne Coupling and Arene C−H Bond Activation Forming a Substituted Butadiene Ligand

Comstock M.C., Shapley J.R.

Organometallics, 1997

25.

10.1021/om050438d

Catalytic C−H Activation of Hydrocarbons by Rhodium(I) and Iridium(I) Complexes with Hemilabile Quinolyl-Cp Ligands

Kohl G., Rudolph R., Pritzkow H., Enders M.

Organometallics, 2005

26.

10.1016/j.jorganchem.2006.03.017

Electronic properties of new homobimetallic anthracene-bridged η5-cyclopentadienyl derivatives of iridium(I) and of the corresponding cation radicals [L2Ir{C5H4CH2(9,10-anthrylene)CH2C5H4}IrL2]+

Bertini F., Calucci L., Cicogna F., Gaddi B., Ingrosso G., Marcaccio M., Marchetti F., Paolucci D., Paolucci F., Pinzino C.

Journal of Organometallic Chemistry, 2006

27.

10.1016/j.ica.2008.04.025

Syntheses and characterization of iridium and rhodium ethylene complexes containing a doubly linked cyclopentadienyl ligand

Chin R.M., Maurer D., Parr M., Allworth N., Schwenker R., Sullivan D., Enabnit S., Brennessel W.

Inorganica Chimica Acta, 2009

28.

10.1016/j.mencom.2016.11.010_bib0060

Lide

CRC Handbook of Chemistry and Physics, 2003

29.

10.1021/om970827a

Cyclopentadienyl and Imide Ligand Transfer from Zirconium to Iridium: Can Early Transition Metal Imido Compounds Be Used as Imide Transfer Reagents?

Holland P.L., Andersen R.A., Bergman R.G.

Organometallics, 1998

30.

10.1016/S0022-328X(96)06886-6

X-ray structures of decamethylplatinocene dication in the crystal of [Pt(η5-C5Me5)2]2+(PF6−)2 and decamethyliridocenium cation in the crystal of [Ir(η5-C5Me5)2]+(BPh4−) · CH2Cl2

Struchkov Y.T., Antipin M.Y., Lyssenko K.A., Gusev O.V., Peganova T.A., Ustynyuk N.A.

Journal of Organometallic Chemistry, 1997

31.

10.1007/s11172-014-0537-3

Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene

Loginov D.A., Belova A.O., Kudinov A.R.

Russian Chemical Bulletin, 2014

32.

10.1016/j.jorganchem.2015.01.022

Cationic iridacarboranes [3-(arene)-3,1,2-IrC2B9H11]+ and [3-(MeCN)3-3,1,2-IrC2B9H11]+: Synthesis, reactivity, and bonding. Catalysis of oxidative coupling of benzoic acid with alkynes

Loginov D.A., Belova A.O., Vologzhanina A.V., Kudinov A.R.

Journal of Organometallic Chemistry, 2015

33.

10.1021/ol005653z

Trifluoromethyl-Substituted Indenyl Rhodium and Iridium Complexes Are Highly Selective Catalysts for Directed Hydroboration Reactions

Brinkman J.A., Nguyen T.T., Sowa J.R.

Organic Letters, 2000

34.

10.1016/j.mencom.2016.11.010_sbref0080b

Alvarez

Organometallics, 2001

35.

10.1016/j.mencom.2016.11.010_sbref0080c

Garon

Dalton Trans., 2009

36.

10.1016/j.mencom.2015.11.012

Synthetic approach to 6-tert-butyl-5-methoxy-2-methylindenyl zirconium ansa-complexes, bridged in 4-position of indenyl fragment

Ivchenko P.V., Nifant’ev I.E., Smetannikov O.V., Ivanyuk A.A., Churakov A.V.

Mendeleev Communications, 2015