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Heterogeneous Jørgensen–Hayashi catalyst for asymmetric Michael addition of malonates to α,β-enals. Cooperative effect with Ca(OTf)2

Anton A Guryev 1
Anton A Guryev
, 
Maksim Viktorovich Anokhin 1
Maksim Viktorovich Anokhin
, 
Alexei Dmitrievich Averin 1
Alexei Dmitrievich Averin
, 
10.1016/j.mencom.2016.11.002
Published 2016-10-27
Communication , Volume 26, Issue 6, 469-470
9
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Guryev A. A. et al. Heterogeneous Jørgensen–Hayashi catalyst for asymmetric Michael addition of malonates to α,β-enals. Cooperative effect with Ca(OTf)2 // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 469-470.
GOST all authors (up to 50) Copy
Guryev A. A., Anokhin M. V., Averin A. D., Beletskaya I. P. Heterogeneous Jørgensen–Hayashi catalyst for asymmetric Michael addition of malonates to α,β-enals. Cooperative effect with Ca(OTf)2 // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 469-470.
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TY - JOUR
DO - 10.1016/j.mencom.2016.11.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.002
TI - Heterogeneous Jørgensen–Hayashi catalyst for asymmetric Michael addition of malonates to α,β-enals. Cooperative effect with Ca(OTf)2
T2 - Mendeleev Communications
AU - Guryev, Anton A
AU - Anokhin, Maksim Viktorovich
AU - Averin, Alexei Dmitrievich
AU - Beletskaya, Irina Petrovna
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 469-470
IS - 6
VL - 26
ER -
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@article{2016_Guryev,
author = {Anton A Guryev and Maksim Viktorovich Anokhin and Alexei Dmitrievich Averin and Irina Petrovna Beletskaya},
title = {Heterogeneous Jørgensen–Hayashi catalyst for asymmetric Michael addition of malonates to α,β-enals. Cooperative effect with Ca(OTf)2},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.002},
number = {6},
pages = {469--470},
doi = {10.1016/j.mencom.2016.11.002}
}
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Guryev, Anton A., et al. “Heterogeneous Jørgensen–Hayashi catalyst for asymmetric Michael addition of malonates to α,β-enals. Cooperative effect with Ca(OTf)2.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 469-470. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.002.

Abstract

Heterogeneous chiral Jørgensen–Hayashi catalyst promotes enantioselective Michael addition of malonates at cinnamic aldehydes. In combination with Ca(OTf)2, it provides high yields (up to 78%) and excellent enantiomeric excesses (up to 99%) of the adducts.

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