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Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals

Nataliya Afanas'evna Keiko 1
Nataliya Afanas'evna Keiko
, 
Nadezhda Viktorovna Vchislo 1
Nadezhda Viktorovna Vchislo
, 
Ekaterina Aleksandrovna Verochkina 1
Ekaterina Aleksandrovna Verochkina
, 
Yuri Aleksandrovich Chuvashev 1
Yuri Aleksandrovich Chuvashev
, 
Lyudmila Ivanovna Larina 1
Lyudmila Ivanovna Larina
10.1016/j.mencom.2016.09.023
Published 2016-09-08
Communication , Volume 26, Issue 5, 431-433
4
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Keiko N. A. et al. Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals // Mendeleev Communications. 2016. Vol. 26. No. 5. pp. 431-433.
GOST all authors (up to 50) Copy
Keiko N. A., Vchislo N. V., Verochkina E. A., Chuvashev Y. A., Larina L. I. Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals // Mendeleev Communications. 2016. Vol. 26. No. 5. pp. 431-433.
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TY - JOUR
DO - 10.1016/j.mencom.2016.09.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.023
TI - Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals
T2 - Mendeleev Communications
AU - Keiko, Nataliya Afanas'evna
AU - Vchislo, Nadezhda Viktorovna
AU - Verochkina, Ekaterina Aleksandrovna
AU - Chuvashev, Yuri Aleksandrovich
AU - Larina, Lyudmila Ivanovna
PY - 2016
DA - 2016/09/08
PB - Mendeleev Communications
SP - 431-433
IS - 5
VL - 26
ER -
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@article{2016_Keiko,
author = {Nataliya Afanas'evna Keiko and Nadezhda Viktorovna Vchislo and Ekaterina Aleksandrovna Verochkina and Yuri Aleksandrovich Chuvashev and Lyudmila Ivanovna Larina},
title = {Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.023},
number = {5},
pages = {431--433},
doi = {10.1016/j.mencom.2016.09.023}
}
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Keiko, Nataliya Afanas'evna, et al. “Hydrolysis of (Z)-2-alkoxy-3-arylpropenals as a short-cut to benzylglyoxals.” Mendeleev Communications, vol. 26, no. 5, Sep. 2016, pp. 431-433. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.023.

Abstract

Hydrolysis of the C=C bond in 2-alkoxy-3-aryl(hetaryl)-propenals, depending upon substituents in the molecule, can proceed according to Markovnikov or Michael rule or with heterolytic opening of the cycle (in the case of 2-alkoxy-3-furylpropenal). Hydrolysis of 3-phenyl substituted alkoxypropenals bearing electron-withdrawing substituents (Cl, NO2) in the p-position has allowed a method for the preparation of corresponding benzylglyoxals (stable in enol form) to be developed.

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