Abstract
Monoclinic and triclinic modifications of nitrosonium nitratonickelate NO[Ni(NO3)3] as well as triclinic modification of nitrosonium nitratocobaltate NO[Co(NO3)3] (isostructural to triclinic NO[Ni(NO3)3]) have been synthesized by a new synthetic approach. Single crystal XRD studies revealed the similarity of all these structures in which octahedrally coordinated metal atoms are connected through NO3- bridges forming three-dimensional distorted cubic framework with NO+ cations located in the framework cavities.
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