Home / Publications / Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines

Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines

Vladimir Alekseevich Kokorekin 1
Vladimir Alekseevich Kokorekin
, 
Rauza Railevna Yaubasarova 1
Rauza Railevna Yaubasarova
,  , 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1016/j.mencom.2016.09.016
Published 2016-09-08
Communication , Volume 26, Issue 5, 413-414
24
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kokorekin V. A. et al. Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines // Mendeleev Communications. 2016. Vol. 26. No. 5. pp. 413-414.
GOST all authors (up to 50) Copy
Kokorekin V. A., Yaubasarova R. R., Neverov S. V., Petrosyan V. A. Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines // Mendeleev Communications. 2016. Vol. 26. No. 5. pp. 413-414.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2016.09.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.016
TI - Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines
T2 - Mendeleev Communications
AU - Kokorekin, Vladimir Alekseevich
AU - Yaubasarova, Rauza Railevna
AU - Neverov, Sergey Vladimirovich
AU - Petrosyan, Vladimir Anushavanovich
PY - 2016
DA - 2016/09/08
PB - Mendeleev Communications
SP - 413-414
IS - 5
VL - 26
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Kokorekin,
author = {Vladimir Alekseevich Kokorekin and Rauza Railevna Yaubasarova and Sergey Vladimirovich Neverov and Vladimir Anushavanovich Petrosyan},
title = {Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.016},
number = {5},
pages = {413--414},
doi = {10.1016/j.mencom.2016.09.016}
}
MLA
Cite this
MLA Copy
Kokorekin, Vladimir Alekseevich, et al. “Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines.” Mendeleev Communications, vol. 26, no. 5, Sep. 2016, pp. 413-414. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.016.

Abstract

Selective thiocyanation (yield 70–90%) at the 3-position of pyrazolo[1,5-a]pyrimidines was performed with thiocyanogen electrochemically generated in situ from NH4SCN in MeCN on a Pt anode. For substrates with higher oxidation potential addition of Lewis acids was necessary.

References

2.
Direct nucleophilic functionalization of C(sp2)–H-bonds in arenes and hetarenes by electrochemical methods
Shchepochkin A.V., Chupakhin O.N., Charushin V.N., Petrosyan V.A.
Russian Chemical Reviews, 2013
3.
10.1016/j.mencom.2016.09.016_bib0015
Ingold
Structure and Mechanism in Organic Chemistry, 1969
6.
Synthesis, chemistry, and biological activity of 5-thiocyanatopyrimidine nucleosides as potential masked thiols
Nagamachi T., Fourrey J.L., Torrence P.F., Waters J.A., Witkop B.
Journal of Medicinal Chemistry, 1974
7.
Design, Synthesis, and Biological Evaluation of Aryloxyethyl Thiocyanate Derivatives against Trypanosoma cruzi
Elhalem E., Bailey B.N., Docampo R., Ujváry I., Szajnman S.H., Rodriguez J.B.
Journal of Medicinal Chemistry, 2002
8.
V. A. Kokorekin, G.V. Ramenskaya, G.M. Rodionova and V. A. Petrosyan, in Proceedings of IV International Scientific-practical Conference ‘High Technologies, Basic and Applied Researches in Physiology and Medicine’, St. Petersburg, Russia, 2012, vol. 1. p. 40 (in Russian).
9.
Synthesis and Antifungal Activity of Arylthiocyanates
Kokorekin V.A., Terent’ev A.O., Ramenskaya G.V., Grammatikova N.É., Rodionova G.M., Ilovaiskii A.I.
Pharmaceutical Chemistry Journal, 2013
10.
10.1016/j.mencom.2016.09.016_bib0050
Wood
1946
11.
10.1016/j.mencom.2016.09.016_bib0055
Guy
1977
12.
10.1016/j.mencom.2016.09.016_bib0060
Nikoofar
Chem. Sci. Trans., 2013
13.
K. E. Rosner, J. Popovici-Muller, Y. Deng, T. Wang and P. J. Curran, US Patent 7196111 B2, 2003.
14.
10.1016/j.mencom.2016.09.016_bib0070
Yang
Agrochemicals, 2013
15.
10.1016/j.mencom.2016.09.016_bib0075
Cauquis
C.R. Acad. Sci. Paris, Ser. C, 1968
17.
Ananikov V.P., Khokhlova E.A., Egorov M.P., Sakharov A.M., Zlotin S.G., Kucherov A.V., Kustov L.M., Gening M.L., Nifantiev N.E.
Mendeleev Communications, 2015
18.
E. Terranova, A. Fadli and A. Lagrange, US Patent 6099593A, 2000.