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Ionic liquid supported 4-HO-Pro-Val derived organocatalysts for asymmetric aldol reactions in the presence of water

Alexander Sergeevich Kucherenko 1
Alexander Sergeevich Kucherenko
, 
Vasily V Perepelkin 1
Vasily V Perepelkin
, 
Galina Mikhailovna Zhdankina 1
Galina Mikhailovna Zhdankina
, 
Galina Valentinovna Kryshtal 1
Galina Valentinovna Kryshtal
, 
Easwar Srinivasan 2
Easwar Srinivasan
, 
Heena Inani 2
Heena Inani
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2016.09.007
Published 2016-09-08
Communication , Volume 26, Issue 5, 388-390
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Kucherenko A. S. et al. Ionic liquid supported 4-HO-Pro-Val derived organocatalysts for asymmetric aldol reactions in the presence of water // Mendeleev Communications. 2016. Vol. 26. No. 5. pp. 388-390.
GOST all authors (up to 50) Copy
Kucherenko A. S., Perepelkin V. V., Zhdankina G. M., Kryshtal G. V., Srinivasan E., Inani H., Zlotin S. G. Ionic liquid supported 4-HO-Pro-Val derived organocatalysts for asymmetric aldol reactions in the presence of water // Mendeleev Communications. 2016. Vol. 26. No. 5. pp. 388-390.
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TY - JOUR
DO - 10.1016/j.mencom.2016.09.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.007
TI - Ionic liquid supported 4-HO-Pro-Val derived organocatalysts for asymmetric aldol reactions in the presence of water
T2 - Mendeleev Communications
AU - Kucherenko, Alexander Sergeevich
AU - Perepelkin, Vasily V
AU - Zhdankina, Galina Mikhailovna
AU - Kryshtal, Galina Valentinovna
AU - Srinivasan, Easwar
AU - Inani, Heena
AU - Zlotin, Sergei Grigorievich
PY - 2016
DA - 2016/09/08
PB - Mendeleev Communications
SP - 388-390
IS - 5
VL - 26
ER -
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@article{2016_Kucherenko,
author = {Alexander Sergeevich Kucherenko and Vasily V Perepelkin and Galina Mikhailovna Zhdankina and Galina Valentinovna Kryshtal and Easwar Srinivasan and Heena Inani and Sergei Grigorievich Zlotin},
title = {Ionic liquid supported 4-HO-Pro-Val derived organocatalysts for asymmetric aldol reactions in the presence of water},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.007},
number = {5},
pages = {388--390},
doi = {10.1016/j.mencom.2016.09.007}
}
MLA
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Kucherenko, Alexander Sergeevich, et al. “Ionic liquid supported 4-HO-Pro-Val derived organocatalysts for asymmetric aldol reactions in the presence of water.” Mendeleev Communications, vol. 26, no. 5, Sep. 2016, pp. 388-390. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.09.007.
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Abstract

Novel (4R)-HO-(2S)-Pro-(S)-Val derivative tagged to 1-methylimidazolium cation and PF6- anion efficiently catalyzes asymmetric aldol reactions of cyclic ketones with aromatic aldehydes in aqueous environment to afford the corresponding aldols in high yield with moderate to high anti-diastereo- (dr up to 99:1) and enantioselectivity (up to 98% ee). The catalyst was recycled 9 times in the same reaction without any decrease in selectivity values.

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