Home / Publications / Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines

Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines

Yurii Vladimirovich Koshchienko 1
Yurii Vladimirovich Koshchienko
, 
Tatyana Andreevna Kuz'menko 1
Tatyana Andreevna Kuz'menko
, 
Anatolii Savel'evich Morkovnik 1
Anatolii Savel'evich Morkovnik
, 
Mikhail Aleksandrovich Kiskin 2
Mikhail Aleksandrovich Kiskin
, 
Grigorii Grigor'evich Alexandrov 2
Grigorii Grigor'evich Alexandrov
10.1016/j.mencom.2016.07.018
Published 2016-07-07
Communication , Volume 26, Issue 4, 320-322
3
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Koshchienko Y. V. et al. Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines // Mendeleev Communications. 2016. Vol. 26. No. 4. pp. 320-322.
GOST all authors (up to 50) Copy
Koshchienko Y. V., Kuz'menko T. A., Morkovnik A. S., Kiskin M. A., Alexandrov G. G. Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines // Mendeleev Communications. 2016. Vol. 26. No. 4. pp. 320-322.
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TY - JOUR
DO - 10.1016/j.mencom.2016.07.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.018
TI - Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines
T2 - Mendeleev Communications
AU - Koshchienko, Yurii Vladimirovich
AU - Kuz'menko, Tatyana Andreevna
AU - Morkovnik, Anatolii Savel'evich
AU - Kiskin, Mikhail Aleksandrovich
AU - Alexandrov, Grigorii Grigor'evich
PY - 2016
DA - 2016/07/07
PB - Mendeleev Communications
SP - 320-322
IS - 4
VL - 26
ER -
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@article{2016_Koshchienko,
author = {Yurii Vladimirovich Koshchienko and Tatyana Andreevna Kuz'menko and Anatolii Savel'evich Morkovnik and Mikhail Aleksandrovich Kiskin and Grigorii Grigor'evich Alexandrov},
title = {Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.018},
number = {4},
pages = {320--322},
doi = {10.1016/j.mencom.2016.07.018}
}
MLA
Cite this
MLA Copy
Koshchienko, Yurii Vladimirovich, et al. “Unexpected domino reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide leading to benzimidazolyl guanidines.” Mendeleev Communications, vol. 26, no. 4, Jul. 2016, pp. 320-322. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.018.

Abstract

Reaction of 3-alkyl-1,2,4-triazolo[1,5-a]benzimidazoles with butylmagnesium bromide follows two hetarylotropic rearrangements to afford 1,2-bis(1H-benzimidazol-2-yl)-1,3-dialkylguanidines and 2-(1’H-1,2’-dibenzimidazol-2-yl)-1,3-dialkylguanidines.

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