Home / Publications / A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12

A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
10.1016/j.mencom.2016.07.015
Published 2016-07-07
Communication , Volume 26, Issue 4, 312-313
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Tamm N. B., Troyanov S. I. A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12 // Mendeleev Communications. 2016. Vol. 26. No. 4. pp. 312-313.
GOST all authors (up to 50) Copy
Tamm N. B., Troyanov S. I. A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12 // Mendeleev Communications. 2016. Vol. 26. No. 4. pp. 312-313.
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TY - JOUR
DO - 10.1016/j.mencom.2016.07.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.015
TI - A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Troyanov, Sergey Igorevich
PY - 2016
DA - 2016/07/07
PB - Mendeleev Communications
SP - 312-313
IS - 4
VL - 26
ER -
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@article{2016_Tamm,
author = {Nadezhda Borisovna Tamm and Sergey Igorevich Troyanov},
title = {A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.015},
number = {4},
pages = {312--313},
doi = {10.1016/j.mencom.2016.07.015}
}
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Tamm, Nadezhda Borisovna, and Sergey Igorevich Troyanov. “A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12.” Mendeleev Communications, vol. 26, no. 4, Jul. 2016, pp. 312-313. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.015.

Abstract

An isomer of C84 fullerene, D3d-C84(24)(CF3)12, has been isolated by the HPLC method from the products of trifluoromethylation of C84 fullerene mixture. Its molecular structure has been determined by a single crystal X-ray diffraction using synchrotron radiation. In the addition pattern, 12 CF3 groups are arranged as a loop of edge-sharing para-C6(CF3)2 hexagons. Isomer D6h-C84(24) has been identified in the form of a derivative for the first time.

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