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Unprecedented polymeric trifluoroacetate palladium–silver complexes: π-complex with η2- and η4-coordinated toluene, as well as a unique seventeen nuclear palladium–silver trifluoroacetate

Andrei Viktorovich Churakov 1
Andrei Viktorovich Churakov
, 
Inessa Aleksandrovna Efimenko 1
Inessa Aleksandrovna Efimenko
, 
Olga Sergeevna Erofeeva 1
Olga Sergeevna Erofeeva
, 
Ludmila G Kuz'mina 1
Ludmila G Kuz'mina
, 
Nina Aleksandrovna Ivanova 1
Nina Aleksandrovna Ivanova
10.1016/j.mencom.2016.07.009
Published 2016-07-07
Communication , Volume 26, Issue 4, 295-297
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Churakov A. V. et al. Unprecedented polymeric trifluoroacetate palladium–silver complexes: π-complex with η2- and η4-coordinated toluene, as well as a unique seventeen nuclear palladium–silver trifluoroacetate // Mendeleev Communications. 2016. Vol. 26. No. 4. pp. 295-297.
GOST all authors (up to 50) Copy
Churakov A. V., Efimenko I. A., Erofeeva O. S., Kuz'mina L. G., Ivanova N. A. Unprecedented polymeric trifluoroacetate palladium–silver complexes: π-complex with η2- and η4-coordinated toluene, as well as a unique seventeen nuclear palladium–silver trifluoroacetate // Mendeleev Communications. 2016. Vol. 26. No. 4. pp. 295-297.
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TY - JOUR
DO - 10.1016/j.mencom.2016.07.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.009
TI - Unprecedented polymeric trifluoroacetate palladium–silver complexes: π-complex with η2- and η4-coordinated toluene, as well as a unique seventeen nuclear palladium–silver trifluoroacetate
T2 - Mendeleev Communications
AU - Churakov, Andrei Viktorovich
AU - Efimenko, Inessa Aleksandrovna
AU - Erofeeva, Olga Sergeevna
AU - Kuz'mina, Ludmila G
AU - Ivanova, Nina Aleksandrovna
PY - 2016
DA - 2016/07/07
PB - Mendeleev Communications
SP - 295-297
IS - 4
VL - 26
ER -
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@article{2016_Churakov,
author = {Andrei Viktorovich Churakov and Inessa Aleksandrovna Efimenko and Olga Sergeevna Erofeeva and Ludmila G Kuz'mina and Nina Aleksandrovna Ivanova},
title = {Unprecedented polymeric trifluoroacetate palladium–silver complexes: π-complex with η2- and η4-coordinated toluene, as well as a unique seventeen nuclear palladium–silver trifluoroacetate},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.009},
number = {4},
pages = {295--297},
doi = {10.1016/j.mencom.2016.07.009}
}
MLA
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Churakov, Andrei Viktorovich, et al. “Unprecedented polymeric trifluoroacetate palladium–silver complexes: π-complex with η2- and η4-coordinated toluene, as well as a unique seventeen nuclear palladium–silver trifluoroacetate.” Mendeleev Communications, vol. 26, no. 4, Jul. 2016, pp. 295-297. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.07.009.

Abstract

The first polynuclear heterodimetallic Pdii–Agi trifluoroacetate π-complex with Agi η2- and η4-coordinated molecules of toluene, namely, PdAg2(μ-TFA)4(η2-Tol)2(μ-η4-Tol)]n and [Pd2Ag4(μ-TFA)8(η2-Tol)2(μ-η4-Tol)]n (TFA = OCOCF3, Tol=toluene) as well as the unique seventeen nuclear Pdii–Agi trifluoroacetate complex Pd5Ag12(H2O)16(μ-TFA)8·7H2O have been synthesized. Their solid-state structure was determined by X-ray method.

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