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Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate

Alexander Olegovich Terent'ev 1, 2
Alexander Olegovich Terent'ev
, 
Mikhail Yuryevich Sharipov 1, 2
Mikhail Yuryevich Sharipov
,  , 
Igor' Borisovich Krylov 1
Igor' Borisovich Krylov
, 
Darya Valeryevna Gaidarenko 2
Darya Valeryevna Gaidarenko
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
10.1016/j.mencom.2016.05.001
Published 2016-04-28
Communication , Volume 26, Issue 3, 226-227
10
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Terent'ev A. O. et al. Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate // Mendeleev Communications. 2016. Vol. 26. No. 3. pp. 226-227.
GOST all authors (up to 50) Copy
Terent'ev A. O., Sharipov M. Y., Glinushkin A. P., Krylov I. B., Gaidarenko D. V., Nikishin G. I. Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate // Mendeleev Communications. 2016. Vol. 26. No. 3. pp. 226-227.
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TY - JOUR
DO - 10.1016/j.mencom.2016.05.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.05.001
TI - Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate
T2 - Mendeleev Communications
AU - Terent'ev, Alexander Olegovich
AU - Sharipov, Mikhail Yuryevich
AU - Glinushkin, Alexey Pavlovich
AU - Krylov, Igor' Borisovich
AU - Gaidarenko, Darya Valeryevna
AU - Nikishin, Gennady Ivanovich
PY - 2016
DA - 2016/04/28
PB - Mendeleev Communications
SP - 226-227
IS - 3
VL - 26
ER -
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@article{2016_Terent'ev,
author = {Alexander Olegovich Terent'ev and Mikhail Yuryevich Sharipov and Alexey Pavlovich Glinushkin and Igor' Borisovich Krylov and Darya Valeryevna Gaidarenko and Gennady Ivanovich Nikishin},
title = {Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.05.001},
number = {3},
pages = {226--227},
doi = {10.1016/j.mencom.2016.05.001}
}
MLA
Cite this
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Terent'ev, Alexander Olegovich, et al. “Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate.” Mendeleev Communications, vol. 26, no. 3, Apr. 2016, pp. 226-227. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.05.001.

Abstract

β-Diketones and β-oxo esters are thiocyanated with the NaSCN/(NH4)2 Ce(NO3)6 system or with pre-generated dirhodanogen. Malonates undergo thiocyanation only with the NaSCN/(NH4)2 Ce(NO3)6 system.

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