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1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure†

Vasiliy Georgievich Shtamburg 1
Vasiliy Georgievich Shtamburg
, 
Svetlana V Shishkina 2
Svetlana V Shishkina
, 
Victor Vasil'evich Shtamburg 1
Victor Vasil'evich Shtamburg
, 
Alexander Vladimirovich Mazepa 3
Alexander Vladimirovich Mazepa
, 
Gulnara Konstantinovna Kadorkina 4
Gulnara Konstantinovna Kadorkina
, 
Remir Grigorevich Kostyanovsky 4
Remir Grigorevich Kostyanovsky
1 Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
2 STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
3 A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
10.1016/j.mencom.2016.03.030
Published 2016-03-02
Communication , Volume 26, Issue 2, 169-171
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Shtamburg V. G. et al. 1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure† // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 169-171.
GOST all authors (up to 50) Copy
Shtamburg V. G., Shishkina S. V., Shtamburg V. V., Mazepa A. V., Kadorkina G. K., Kostyanovsky R. G. 1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure† // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 169-171.
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TY - JOUR
DO - 10.1016/j.mencom.2016.03.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.030
TI - 1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure†
T2 - Mendeleev Communications
AU - Shtamburg, Vasiliy Georgievich
AU - Shishkina, Svetlana V
AU - Shtamburg, Victor Vasil'evich
AU - Mazepa, Alexander Vladimirovich
AU - Kadorkina, Gulnara Konstantinovna
AU - Kostyanovsky, Remir Grigorevich
PY - 2016
DA - 2016/03/02
PB - Mendeleev Communications
SP - 169-171
IS - 2
VL - 26
ER -
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@article{2016_Shtamburg,
author = {Vasiliy Georgievich Shtamburg and Svetlana V Shishkina and Victor Vasil'evich Shtamburg and Alexander Vladimirovich Mazepa and Gulnara Konstantinovna Kadorkina and Remir Grigorevich Kostyanovsky},
title = {1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure†},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.030},
number = {2},
pages = {169--171},
doi = {10.1016/j.mencom.2016.03.030}
}
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Shtamburg, Vasiliy Georgievich, et al. “1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure†.” Mendeleev Communications, vol. 26, no. 2, Mar. 2016, pp. 169-171. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.030.

Abstract

N-Alkoxy-N-chlorocarbamates react with 4-dimethyl-aminopyridine yielding 1-alkoxyamino-4-dimethylamino-pyridinium chlorides, new type of O–N–N+ geminal systems. The XRD studies of two representative 1-alkoxyamino-pyridinium chlorides revealed the high pyramidal configuration of the central nitrogen atom in O–N–N+ geminal system.

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