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Phase transitions and proton conductivity in hafnium hydrogen phosphate with the NASICON structure

Daria Yur'evna Voropaeva 1
Daria Yur'evna Voropaeva
, 
Mariya Aleksandrovna Moshareva 1
Mariya Aleksandrovna Moshareva
, 
Andrey B Il'in 2
Andrey B Il'in
, 
Svetlana Aleksandrovna Novikova 1
Svetlana Aleksandrovna Novikova
, 
Andrei Borisovich Yaroslavtsev 1
Andrei Borisovich Yaroslavtsev
10.1016/j.mencom.2016.03.024
Published 2016-03-02
Communication , Volume 26, Issue 2, 152-153
5
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Voropaeva D. Y. et al. Phase transitions and proton conductivity in hafnium hydrogen phosphate with the NASICON structure // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 152-153.
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Voropaeva D. Y., Moshareva M. A., Il'in A. B., Novikova S. A., Yaroslavtsev A. B. Phase transitions and proton conductivity in hafnium hydrogen phosphate with the NASICON structure // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 152-153.
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TY - JOUR
DO - 10.1016/j.mencom.2016.03.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.024
TI - Phase transitions and proton conductivity in hafnium hydrogen phosphate with the NASICON structure
T2 - Mendeleev Communications
AU - Voropaeva, Daria Yur'evna
AU - Moshareva, Mariya Aleksandrovna
AU - Il'in, Andrey B
AU - Novikova, Svetlana Aleksandrovna
AU - Yaroslavtsev, Andrei Borisovich
PY - 2016
DA - 2016/03/02
PB - Mendeleev Communications
SP - 152-153
IS - 2
VL - 26
ER -
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@article{2016_Voropaeva,
author = {Daria Yur'evna Voropaeva and Mariya Aleksandrovna Moshareva and Andrey B Il'in and Svetlana Aleksandrovna Novikova and Andrei Borisovich Yaroslavtsev},
title = {Phase transitions and proton conductivity in hafnium hydrogen phosphate with the NASICON structure},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.024},
number = {2},
pages = {152--153},
doi = {10.1016/j.mencom.2016.03.024}
}
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Voropaeva, Daria Yur'evna, et al. “Phase transitions and proton conductivity in hafnium hydrogen phosphate with the NASICON structure.” Mendeleev Communications, vol. 26, no. 2, Mar. 2016, pp. 152-153. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.024.

Abstract

Triclinic NASICON-type hafnium hydrogen phosphate HHf2(PO4)3·0.5H2O was obtained by ion exchange from LiHf2(PO4)3. The dehydration of HHf2(PO4)3·0.5H2O (∼ 400 K) followed by a triclinic-rhombohedral phase transition (∼470 K) was observed, and the resulting HHf2(PO4)3 was stable up to 870 K. The proton conductivity of the sample was 4.7×10–7 Ohm–1 cm–1 at 773 K.

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