Home / Publications / Synthesis and X-ray structure of C88(7)(CF3)12/16

Synthesis and X-ray structure of C88(7)(CF3)12/16

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
10.1016/j.mencom.2016.03.020
Published 2016-03-02
Communication , Volume 26, Issue 2, 141-142
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Tamm N. B., Troyanov S. I. Synthesis and X-ray structure of C88(7)(CF3)12/16 // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 141-142.
GOST all authors (up to 50) Copy
Tamm N. B., Troyanov S. I. Synthesis and X-ray structure of C88(7)(CF3)12/16 // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 141-142.
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TY - JOUR
DO - 10.1016/j.mencom.2016.03.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.020
TI - Synthesis and X-ray structure of C88(7)(CF3)12/16
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Troyanov, Sergey Igorevich
PY - 2016
DA - 2016/03/02
PB - Mendeleev Communications
SP - 141-142
IS - 2
VL - 26
ER -
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@article{2016_Tamm,
author = {Nadezhda Borisovna Tamm and Sergey Igorevich Troyanov},
title = {Synthesis and X-ray structure of C88(7)(CF3)12/16},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.020},
number = {2},
pages = {141--142},
doi = {10.1016/j.mencom.2016.03.020}
}
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Tamm, Nadezhda Borisovna, and Sergey Igorevich Troyanov. “Synthesis and X-ray structure of C88(7)(CF3)12/16.” Mendeleev Communications, vol. 26, no. 2, Mar. 2016, pp. 141-142. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.020.

Abstract

Compounds C88(7)(CF3)12 and C88(7)(CF3)16 were isolated by HPLC from the trifluoromethylation products of a mixture of C88 isomers. An X-ray diffraction study revealed that the trifluoromethylation patterns are characterized by the additions in edge-sharing para and meta C6(CF3)2 hexagons and the presence of stabilizing isolated and partially isolated C=C bonds on the fullerene cage.

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