Home / Publications / First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel]

First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel]

Il'yas Faridovich Sakhapov 1, 2
Il'yas Faridovich Sakhapov
, 
Zufar Nafigullovich Gafurov 1, 2
Zufar Nafigullovich Gafurov
, 
Vasily Mikhailovich Babaev 1
Vasily Mikhailovich Babaev
, 
Ildar Khamidovich Rizvanov 1
Ildar Khamidovich Rizvanov
, 
Alexey Borisovich Dobrynin 1
Alexey Borisovich Dobrynin
, 
Dmitry Borisovich Krivolapov 1
Dmitry Borisovich Krivolapov
,  ,  , 
Dmitry Grigorievich Yakhvarov 1, 2
Dmitry Grigorievich Yakhvarov
10.1016/j.mencom.2016.03.016
Published 2016-03-02
Communication , Volume 26, Issue 2, 131-133
17
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Sakhapov I. F. et al. First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel] // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 131-133.
GOST all authors (up to 50) Copy
Sakhapov I. F., Gafurov Z. N., Babaev V. M., Rizvanov I. K., Dobrynin A. B., Krivolapov D. B., Khayarov K. R., Sinyashin O. G., Yakhvarov D. G. First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel] // Mendeleev Communications. 2016. Vol. 26. No. 2. pp. 131-133.
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TY - JOUR
DO - 10.1016/j.mencom.2016.03.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.016
TI - First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel]
T2 - Mendeleev Communications
AU - Sakhapov, Il'yas Faridovich
AU - Gafurov, Zufar Nafigullovich
AU - Babaev, Vasily Mikhailovich
AU - Rizvanov, Ildar Khamidovich
AU - Dobrynin, Alexey Borisovich
AU - Krivolapov, Dmitry Borisovich
AU - Khayarov, Khasan Rafaelevich
AU - Sinyashin, Oleg Gerol'dovich
AU - Yakhvarov, Dmitry Grigorievich
PY - 2016
DA - 2016/03/02
PB - Mendeleev Communications
SP - 131-133
IS - 2
VL - 26
ER -
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@article{2016_Sakhapov,
author = {Il'yas Faridovich Sakhapov and Zufar Nafigullovich Gafurov and Vasily Mikhailovich Babaev and Ildar Khamidovich Rizvanov and Alexey Borisovich Dobrynin and Dmitry Borisovich Krivolapov and Khasan Rafaelevich Khayarov and Oleg Gerol'dovich Sinyashin and Dmitry Grigorievich Yakhvarov},
title = {First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel]},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.016},
number = {2},
pages = {131--133},
doi = {10.1016/j.mencom.2016.03.016}
}
MLA
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Sakhapov, Il'yas Faridovich, et al. “First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel].” Mendeleev Communications, vol. 26, no. 2, Mar. 2016, pp. 131-133. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.03.016.

Abstract

The electrochemical reduction of [NiBr2(bpy)] (bpy is 2,2’-bipyridine) complex in the presence of 2,4,6-tricyclohexylphenylbromide (TchpBr) in undivided electrochemical cell supplied with a sacrificial nickel anode results in the one-pot formation of an organonickel complex [NiBr(Tchp)(bpy)] bearing three cyclic substituents in the s-bonded aromatic ring. The synthesized complex was characterized by various methods including single crystal X-ray analysis.

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