Home / Publications / Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones

Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones

Gumer Yusupovich Ishmuratov 1
Gumer Yusupovich Ishmuratov
, 
Vadim Salavatovich Tukhvatshin 2
Vadim Salavatovich Tukhvatshin
, 
Marina Petrovna Yakovleva 2
Marina Petrovna Yakovleva
, 
Ivan Valentinovich Vakulin 2
Ivan Valentinovich Vakulin
, 
Rinat Rafaisovich Muslukhov 1
Rinat Rafaisovich Muslukhov
, 
Pavel Aleksandrovich Pasko 2
Pavel Aleksandrovich Pasko
, 
Rifkat Faatovich Talipov 2
Rifkat Faatovich Talipov
10.1016/j.mencom.2016.01.032
Published 2015-12-30
Communication , Volume 26, Issue 1, 81-82
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Ishmuratov G. Y. et al. Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones // Mendeleev Communications. 2015. Vol. 26. No. 1. pp. 81-82.
GOST all authors (up to 50) Copy
Ishmuratov G. Y., Tukhvatshin V. S., Yakovleva M. P., Vakulin I. V., Muslukhov R. R., Pasko P. A., Talipov R. F. Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones // Mendeleev Communications. 2015. Vol. 26. No. 1. pp. 81-82.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2016.01.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.01.032
TI - Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones
T2 - Mendeleev Communications
AU - Ishmuratov, Gumer Yusupovich
AU - Tukhvatshin, Vadim Salavatovich
AU - Yakovleva, Marina Petrovna
AU - Vakulin, Ivan Valentinovich
AU - Muslukhov, Rinat Rafaisovich
AU - Pasko, Pavel Aleksandrovich
AU - Talipov, Rifkat Faatovich
PY - 2015
DA - 2015/12/30
PB - Mendeleev Communications
SP - 81-82
IS - 1
VL - 26
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Ishmuratov,
author = {Gumer Yusupovich Ishmuratov and Vadim Salavatovich Tukhvatshin and Marina Petrovna Yakovleva and Ivan Valentinovich Vakulin and Rinat Rafaisovich Muslukhov and Pavel Aleksandrovich Pasko and Rifkat Faatovich Talipov},
title = {Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones},
journal = {Mendeleev Communications},
year = {2015},
volume = {26},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.01.032},
number = {1},
pages = {81--82},
doi = {10.1016/j.mencom.2016.01.032}
}
MLA
Cite this
MLA Copy
Ishmuratov, Gumer Yusupovich, et al. “Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones.” Mendeleev Communications, vol. 26, no. 1, Dec. 2015, pp. 81-82. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.01.032.

Abstract

Prolonged treatment of menth-4-en-3-yl sulfides with H2O2 in acidic medium leads to saturated menthan-3-yl sulfones, the same products having been obtained from menth-4-en-3-yl sulfoxides in acidic medium in the absence of H2O2. The mechanism was evaluated by quantum chemical calculations.

References

1.
Konstantinova L.S., Amelichev S.A., Zlotin S.G., Struchkova M.I., Godovikova T.I., Rakitin O.A.
Mendeleev Communications, 2015
2.
Asymmetric oxidation of verbenone ethylene dithioacetal
Timshina A.V., Rubtsova S.A., Frolova L.L., Alekseev I.N., Slepukhin P.A., Kuchin A.V.
Russian Journal of Organic Chemistry, 2009
3.
10.1016/j.mencom.2016.01.032_bib0015
Ishmuratov
Butlerovskie Soobshcheniya, 2012
4.
Thiylation of (R)-4-Menthen-3-one and Its Derivatives
Ishmuratov G.Y., Tukhvatshin V.S., Muslukhov R.R., Yakovleva M.P., Allagulova A.V., Latypova E.R., Talipov R.F.
Chemistry of Natural Compounds, 2013
5.
Direct diastereoselective addition of l -menthol to activated 1,2,4-triazin-5(4 H )-one
Chupakhin O.N., Zyryanov G.V., Rusinov V.L., Krasnov V.P., Levit G.L., Korolyova M.A., Kodess M.I.
Tetrahedron Letters, 2001
7.
10.1016/j.mencom.2016.01.032_bib0035
Syrlybaeva
J. Struct. Chem. (Engl. Transl.), 2010
8.
10.1016/j.mencom.2016.01.032_bib0040
Talipov
Vestn. Bashkir. Univ., 2008
9.
A. A. Granovsky, http://classic.chem.msu/gran/gamess/index.html