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Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands

Eugeny Petrovich Ivakhnenko 1
Eugeny Petrovich Ivakhnenko
, 
Vladimir Ivanovich Simakov 1
Vladimir Ivanovich Simakov
, 
Pavel Anatol'evich Knyazev 1
Pavel Anatol'evich Knyazev
, 
Galina Vladislavovna Romanenko 2
Galina Vladislavovna Romanenko
, 
Artem Stepanovich Bogomyakov 2
Artem Stepanovich Bogomyakov
, 
Vladimir Isaakovich Minkin 3
Vladimir Isaakovich Minkin
10.1016/j.mencom.2016.01.019
Published 2015-12-30
Communication , Volume 26, Issue 1, 49-51
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Ivakhnenko E. P. et al. Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands // Mendeleev Communications. 2015. Vol. 26. No. 1. pp. 49-51.
GOST all authors (up to 50) Copy
Ivakhnenko E. P., Simakov V. I., Knyazev P. A., Romanenko G. V., Bogomyakov A. S., Minkin V. I. Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands // Mendeleev Communications. 2015. Vol. 26. No. 1. pp. 49-51.
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TY - JOUR
DO - 10.1016/j.mencom.2016.01.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.01.019
TI - Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands
T2 - Mendeleev Communications
AU - Ivakhnenko, Eugeny Petrovich
AU - Simakov, Vladimir Ivanovich
AU - Knyazev, Pavel Anatol'evich
AU - Romanenko, Galina Vladislavovna
AU - Bogomyakov, Artem Stepanovich
AU - Minkin, Vladimir Isaakovich
PY - 2015
DA - 2015/12/30
PB - Mendeleev Communications
SP - 49-51
IS - 1
VL - 26
ER -
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@article{2015_Ivakhnenko,
author = {Eugeny Petrovich Ivakhnenko and Vladimir Ivanovich Simakov and Pavel Anatol'evich Knyazev and Galina Vladislavovna Romanenko and Artem Stepanovich Bogomyakov and Vladimir Isaakovich Minkin},
title = {Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands},
journal = {Mendeleev Communications},
year = {2015},
volume = {26},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.01.019},
number = {1},
pages = {49--51},
doi = {10.1016/j.mencom.2016.01.019}
}
MLA
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Ivakhnenko, Eugeny Petrovich, et al. “Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands.” Mendeleev Communications, vol. 26, no. 1, Dec. 2015, pp. 49-51. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.01.019.

Abstract

A new GdIII complex with the tridentate chelating redox ligand 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone was synthesized and studied by X-ray crystallography, ESR spectroscopy and magnetic measurements. The rigid tricyclic framework of the ligands ensures the formation of a nine-coordinate environment of GdIII surrounded by three nitrogen and six oxygen atoms in the form of a tricapped trigonal prism.

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