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Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement

Alexander Georgievich Badamshin 1, 2
Alexander Georgievich Badamshin
, 
Leonid Vasilevich Spirikhin 2
Leonid Vasilevich Spirikhin
, 
Rinat Faritovich Salikov 3
Rinat Faritovich Salikov
, 
Vladimir Anatol'evich Dokichev 1, 2
Vladimir Anatol'evich Dokichev
, 
10.1016/j.mencom.2015.11.013
Published 2015-11-09
Communication , Volume 25, Issue 6, 438-439
3
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Badamshin A. G. et al. Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement // Mendeleev Communications. 2015. Vol. 25. No. 6. pp. 438-439.
GOST all authors (up to 50) Copy
Badamshin A. G., Spirikhin L. V., Salikov R. F., Dokichev V. A., Tomilov Y. V. Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement // Mendeleev Communications. 2015. Vol. 25. No. 6. pp. 438-439.
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TY - JOUR
DO - 10.1016/j.mencom.2015.11.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.11.013
TI - Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement
T2 - Mendeleev Communications
AU - Badamshin, Alexander Georgievich
AU - Spirikhin, Leonid Vasilevich
AU - Salikov, Rinat Faritovich
AU - Dokichev, Vladimir Anatol'evich
AU - Tomilov, Yury Vasil'evich
PY - 2015
DA - 2015/11/09
PB - Mendeleev Communications
SP - 438-439
IS - 6
VL - 25
ER -
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@article{2015_Badamshin,
author = {Alexander Georgievich Badamshin and Leonid Vasilevich Spirikhin and Rinat Faritovich Salikov and Vladimir Anatol'evich Dokichev and Yury Vasil'evich Tomilov},
title = {Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.11.013},
number = {6},
pages = {438--439},
doi = {10.1016/j.mencom.2015.11.013}
}
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Badamshin, Alexander Georgievich, et al. “Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement.” Mendeleev Communications, vol. 25, no. 6, Nov. 2015, pp. 438-439. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.11.013.

Abstract

N-Allyl-N-methylanilines react with methyl diazoacetate or diazoacetone in the presence of Y, Sc or Sm triflates to give the corresponding methyl N-(2-allylaryl)-N-methylglycinates or 2-allyl-N-methyl-N-(2-oxopropyl)aniline. The formation of these compounds involves the aza-Claisen rearrangement.

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