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Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers

Konstantin Sergeevich Rodygin 1
Konstantin Sergeevich Rodygin
, 
Anton Alekseevich Kostin 1
Anton Alekseevich Kostin
, 
Valentin Pavlovich Ananikov 1, 2
Valentin Pavlovich Ananikov
10.1016/j.mencom.2015.11.004
Published 2015-11-09
Communication , Volume 25, Issue 6, 415-416
26
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Rodygin K. S., Kostin A. A., Ananikov V. P. Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers // Mendeleev Communications. 2015. Vol. 25. No. 6. pp. 415-416.
GOST all authors (up to 50) Copy
Rodygin K. S., Kostin A. A., Ananikov V. P. Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers // Mendeleev Communications. 2015. Vol. 25. No. 6. pp. 415-416.
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TY - JOUR
DO - 10.1016/j.mencom.2015.11.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.11.004
TI - Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers
T2 - Mendeleev Communications
AU - Rodygin, Konstantin Sergeevich
AU - Kostin, Anton Alekseevich
AU - Ananikov, Valentin Pavlovich
PY - 2015
DA - 2015/11/09
PB - Mendeleev Communications
SP - 415-416
IS - 6
VL - 25
ER -
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@article{2015_Rodygin,
author = {Konstantin Sergeevich Rodygin and Anton Alekseevich Kostin and Valentin Pavlovich Ananikov},
title = {Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.11.004},
number = {6},
pages = {415--416},
doi = {10.1016/j.mencom.2015.11.004}
}
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Rodygin, Konstantin Sergeevich, et al. “Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers.” Mendeleev Communications, vol. 25, no. 6, Nov. 2015, pp. 415-416. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.11.004.

Abstract

Calcium carbide was studied as a useful solid-state reagent to incorporate acetylene unit into synthetic procedures. Atom-economic thiol-yne click reaction was successfully performed with single and double additions. Heterocyclic thiols and aliphatic dithiols reacted with acetylene generated in situ from calcium carbide to afford corresponding vinyl sulfides and bis(thiovinyl)ethers in good to high yields.

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