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Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts

, 
Olga Vasil'evna Turova 1
Olga Vasil'evna Turova
,  , 
Alexandr Konstantinovich Khudorozhkov 2
Alexandr Konstantinovich Khudorozhkov
, 
Valerii Ivanovich Bukhtiyarov 2
Valerii Ivanovich Bukhtiyarov
, 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
10.1016/j.mencom.2015.09.017
Published 2015-09-10
Communication , Volume 25, Issue 5, 367-369
17
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Markov P. V. et al. Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts // Mendeleev Communications. 2015. Vol. 25. No. 5. pp. 367-369.
GOST all authors (up to 50) Copy
Markov P. V., Turova O. V., Mashkovsky I. S., Khudorozhkov A. K., Bukhtiyarov V. I., Stakheev A. Y. Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts // Mendeleev Communications. 2015. Vol. 25. No. 5. pp. 367-369.
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TY - JOUR
DO - 10.1016/j.mencom.2015.09.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.017
TI - Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts
T2 - Mendeleev Communications
AU - Markov, Pavel Viktorovich
AU - Turova, Olga Vasil'evna
AU - Mashkovsky, Igor' Sergeevich
AU - Khudorozhkov, Alexandr Konstantinovich
AU - Bukhtiyarov, Valerii Ivanovich
AU - Stakheev, Aleksandr Yurevich
PY - 2015
DA - 2015/09/10
PB - Mendeleev Communications
SP - 367-369
IS - 5
VL - 25
ER -
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@article{2015_Markov,
author = {Pavel Viktorovich Markov and Olga Vasil'evna Turova and Igor' Sergeevich Mashkovsky and Alexandr Konstantinovich Khudorozhkov and Valerii Ivanovich Bukhtiyarov and Aleksandr Yurevich Stakheev},
title = {Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.017},
number = {5},
pages = {367--369},
doi = {10.1016/j.mencom.2015.09.017}
}
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Markov, Pavel Viktorovich, et al. “Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts.” Mendeleev Communications, vol. 25, no. 5, Sep. 2015, pp. 367-369. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.017.

Abstract

The selectivity of liquid phase semihydrogenation of diphenylacetylene for cis-stilbene is remarkably improved by increasing Pd particle size due to different structure sensitivity of alkyne and alkene hydrogenation steps.

References

1.
H.-U. Blaser, A. Schnyder, H. Steiner, F. Rossler and P. Baumeister, in Handbook of Heterogeneous Catalysis, eds. G. Ertl, H. Knözinger, F. Schüth and J. Weitkamp, Wiley-VCH, Weinheim, 2008, vol. 8, p. 3298.
2.
Effect of catalyst synthesis parameters on the metal particle size
Mäki-Arvela P., Murzin D.Y.
Applied Catalysis A: General, 2013
3.
Liquid-phase hydrogenation of diphenylacetylene on Pd-Au/Al2O3 bimetallic catalysts
Stakheev A.Y., Moroz B.L., Mashkovsky I.S., Markov P.V., Turova O.V., Tkachenko O.P., Pyryaev P.A., Bukhtiyarov V.I.
Russian Chemical Bulletin, 2015
4.
Ananikov V.P., Khokhlova E.A., Egorov M.P., Sakharov A.M., Zlotin S.G., Kucherov A.V., Kustov L.M., Gening M.L., Nifantiev N.E.
Mendeleev Communications, 2015
5.
Catalysis by Supported Metals
Boudart M.
Advances in Catalysis, 1969
13.
Selective hydrogenation of acetylene in ethylene feedstocks on Pd catalysts
Duca D., Frusteri F., Parmaliana A., Deganello G.
Applied Catalysis A: General, 1996
18.
W. Palczewska, in Hydrogen Effects in Catalysis, eds. Z. Paal and P. G. Menon, Marcel Dekker, New York, 1988, p. 381.
19.
Specific features of the catalytic behavior of supported palladium nanoparticles in heterogeneous catalytic reactions
Stakheev A.Y., Mashkovskii I.S., Baeva G.N., Telegina N.S.
Russian Journal of General Chemistry, 2010
20.
Development of new methods in modern selective organic synthesis: Preparation of functionalized molecules with atomic precision
Ananikov V.P., Khemchyan L.L., Ivanova Y.V., Bukhtiyarov V.I., Sorokin A.M., Prosvirin I.P., Vatsadze S.Z., Medved'ko A.V., Nuriev V.N., Dilman A.D., Levin V.V., Koptyug I.V., Kovtunov K.V., Zhivonitko V.V., Likholobov V.A., et. al.
Russian Chemical Reviews, 2014
22.
Particle Size Effect on CH4 Oxidation Over Noble Metals: Comparison of Pt and Pd Catalysts
Stakheev A.Y., Batkin A.M., Teleguina N.S., Bragina G.O., Zaikovsky V.I., Prosvirin I.P., Khudorozhkov A.K., Bukhtiyarov V.I.
Topics in Catalysis, 2013
24.
P. V. Markov, G.O. Bragina, G.N. Baeva, O.P. Tkachenko, I.S. Mashkovsky, I.A. Yakushev, N. Yu. Kozitsyna, M.N. Vargaftik and A. Yu. Stakheev, Kinet. Katal., 2015, in press.
25.
Palladium supported catalysts for the selective hydrogenation of sunflower oil
Nohair B., Especel C., Lafaye G., Marécot P., Hoang L.C., Barbier J.
Journal of Molecular Catalysis A Chemical, 2005
26.
Structure-Reactivity Relationships on Supported Metal Model Catalysts: Adsorption and Reaction of Ethene and Hydrogen on Pd/Al2O3/NiAl(110)
Shaikhutdinov S., Heemeier M., Bäumer M., Lear T., Lennon D., Oldman R.J., Jackson S.D., Freund H.-.
Journal of Catalysis, 2001
28.
Exchange reactions of hydrogen on metallic catalysts
Horiuti I., Polanyi M.
Transactions of the Faraday Society, 1934