Home / Publications / [2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes

[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes

Pavel Petrovich Chapala 1
Pavel Petrovich Chapala
, 
Maksim Vladimirovich Bermeshev 1
Maksim Vladimirovich Bermeshev
, 
Valentin Georgievich Lakhtin 2
Valentin Georgievich Lakhtin
, 
Alexander Mikhailovich Genaev 3
Alexander Mikhailovich Genaev
, 
Alexander Nikolaevich Tavtorkin 1
Alexander Nikolaevich Tavtorkin
, 
Evgenii Shmerovich Finkelshtein 1
Evgenii Shmerovich Finkelshtein
10.1016/j.mencom.2015.09.008
Published 2015-09-10
Communication , Volume 25, Issue 5, 344-345
12
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Chapala P. P. et al. [2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes // Mendeleev Communications. 2015. Vol. 25. No. 5. pp. 344-345.
GOST all authors (up to 50) Copy
Chapala P. P., Bermeshev M. V., Lakhtin V. G., Genaev A. M., Tavtorkin A. N., Finkelshtein E. S. [2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes // Mendeleev Communications. 2015. Vol. 25. No. 5. pp. 344-345.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2015.09.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.008
TI - [2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes
T2 - Mendeleev Communications
AU - Chapala, Pavel Petrovich
AU - Bermeshev, Maksim Vladimirovich
AU - Lakhtin, Valentin Georgievich
AU - Genaev, Alexander Mikhailovich
AU - Tavtorkin, Alexander Nikolaevich
AU - Finkelshtein, Evgenii Shmerovich
PY - 2015
DA - 2015/09/10
PB - Mendeleev Communications
SP - 344-345
IS - 5
VL - 25
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Chapala,
author = {Pavel Petrovich Chapala and Maksim Vladimirovich Bermeshev and Valentin Georgievich Lakhtin and Alexander Mikhailovich Genaev and Alexander Nikolaevich Tavtorkin and Evgenii Shmerovich Finkelshtein},
title = {[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.008},
number = {5},
pages = {344--345},
doi = {10.1016/j.mencom.2015.09.008}
}
MLA
Cite this
MLA Copy
Chapala, Pavel Petrovich, et al. “[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes.” Mendeleev Communications, vol. 25, no. 5, Sep. 2015, pp. 344-345. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.008.

Abstract

[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to trissilylated ethenes Cl3 – nMenSiCH=CSiMenCl3 – n(SiMe3 – nCln) (n = 1, 2) at 95°C affords 3,3,4-trissilylated exo-tricyclo[4.2.1.02,5]non-7-enes. Tetrakis(trichlorosilyl)ethene does not react with quadricyclane.

References

1.
Synthetic Chemistry of Quadricyclane
Petrov V., Vasil'ev N.
Current Organic Synthesis, 2006
2.
10.1016/j.mencom.2015.09.008_sbref0010a
Grubbs
Wiley-VCH, Weinheim, 2008
3.
Substituted polynorbornenes as promising materials for gas separation membranes
Finkelshtein E.S., Bermeshev M.V., Gringolts M.L., Starannikova L.E., Yampolskii Y.P.
Russian Chemical Reviews, 2011
4.
Regio- and stereospecific [2.pi. + 2.sigma. + 2.sigma.] cycloaddition reaction of quadricyclane
Tabushi I., Yamamura K., Yoshida Z.
Journal of the American Chemical Society, 1972
5.
New Amorphous Fluoropolymers of Tetrafluoroethylene with Fluorinated and Non-Fluorinated Tricyclononenes. Semiconductor Photoresists for Imaging at 157 and 193 nm
Feiring A.E., Crawford M.K., Farnham W.B., Feldman J., French R.H., Junk C.P., Leffew K.W., Petrov V.A., Qiu W., Schadt F.L., Tran H.V., Zumsteg F.C.
Macromolecules, 2006
6.
Synthesis and gas permeation parameters of metathesis polytricyclononenes with pendant Me3E-groups (E = C, Si, Ge)
Bermeshev M., Bulgakov B., Starannikova L., Dibrov G., Chapala P., Demchuk D., Yampolskii Y., Finkelshtein E.
Journal of Applied Polymer Science, 2014
7.
Glassy Polynorbornenes with Si–O–Si Containing Side Groups. Novel Materials for Hydrocarbon Membrane Separation
Bermeshev M.V., Syromolotov A.V., Starannikova L.E., Gringolts M.L., Lakhtin V.G., Yampolskii Y.P., Finkelshtein E.S.
Macromolecules, 2013
8.
10.1016/j.mencom.2015.09.008_bib0030
Scheludyakov
Zh. Obshch. Khim., 1982
9.
Experimental and Theoretical Study of [2σ + 2σ + 2π]–Cycloaddition of Quadricyclane and Ethylenes Containing Three Silyl-Groups
Bermeshev M., Chapala P., Lakhtin V., Genaev A., Filatova M., Peregudov A., Utegenov K., Ustynyuk N., Finkelshtein E.
Silicon, 2014
10.
Synthesis and Molecular Structure of Silylated Ethenes and Acetylenes
Rüdinger C., Beruda H., Schmidbaur H.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1994
11.
10.1016/j.mencom.2015.09.008_bib0045
Petrov
Zh. Obshch. Khim., 1956
12.
Synthesis of silicon-substituted tricyclononenes
Bermeshev M.V., Syromolotov A.V., Gringolts M.L., Lakhtin V.G., Finkelshtein E.S.
Tetrahedron Letters, 2011
14.
Generalized Gradient Approximation Made Simple
Perdew J.P., Burke K., Ernzerhof M.
Physical Review Letters, 1996