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GaCl3-mediated acyclic dimerization of donor–acceptor cyclopropanes using 1,2-dipole reactivity

Roman Aleksandrovich Novikov 1
Roman Aleksandrovich Novikov
, 
Anna Vadimovna Tarasova 1
Anna Vadimovna Tarasova
, 
10.1016/j.mencom.2015.09.007
Published 2015-09-10
Communication , Volume 25, Issue 5, 341-343
17
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Novikov R. A., Tarasova A. V., Tomilov Y. V. GaCl3-mediated acyclic dimerization of donor–acceptor cyclopropanes using 1,2-dipole reactivity // Mendeleev Communications. 2015. Vol. 25. No. 5. pp. 341-343.
GOST all authors (up to 50) Copy
Novikov R. A., Tarasova A. V., Tomilov Y. V. GaCl3-mediated acyclic dimerization of donor–acceptor cyclopropanes using 1,2-dipole reactivity // Mendeleev Communications. 2015. Vol. 25. No. 5. pp. 341-343.
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TY - JOUR
DO - 10.1016/j.mencom.2015.09.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.007
TI - GaCl3-mediated acyclic dimerization of donor–acceptor cyclopropanes using 1,2-dipole reactivity
T2 - Mendeleev Communications
AU - Novikov, Roman Aleksandrovich
AU - Tarasova, Anna Vadimovna
AU - Tomilov, Yury Vasil'evich
PY - 2015
DA - 2015/09/10
PB - Mendeleev Communications
SP - 341-343
IS - 5
VL - 25
ER -
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@article{2015_Novikov,
author = {Roman Aleksandrovich Novikov and Anna Vadimovna Tarasova and Yury Vasil'evich Tomilov},
title = {GaCl3-mediated acyclic dimerization of donor–acceptor cyclopropanes using 1,2-dipole reactivity},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.007},
number = {5},
pages = {341--343},
doi = {10.1016/j.mencom.2015.09.007}
}
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Novikov, Roman Aleksandrovich, et al. “GaCl3-mediated acyclic dimerization of donor–acceptor cyclopropanes using 1,2-dipole reactivity.” Mendeleev Communications, vol. 25, no. 5, Sep. 2015, pp. 341-343. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.09.007.

Abstract

A new type of dimerization of 2-arylcyclopropane-1,1-dicarboxylates in the presence of anhydrous GaCl3 to give acyclic dimers, viz., substituted pent-2-ene-1,1,5,5-tetracarboxylates, occurs at room temperature. In this reaction, one molecule of the donor–acceptor cyclopropane manifests a non-classical reactivity and serves as a 1,2-dipole.

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