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Synthesis and X-ray structure of C2-C96(176)(CF3)18

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
Kerstin Scheurell 2
Kerstin Scheurell
, 
Erhard Kemnitz 2
Erhard Kemnitz
, 
10.1016/j.mencom.2015.07.015
Published 2015-07-08
Communication , Volume 25, Issue 4, 275-276
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Tamm N. B. et al. Synthesis and X-ray structure of C2-C96(176)(CF3)18 // Mendeleev Communications. 2015. Vol. 25. No. 4. pp. 275-276.
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Tamm N. B., Scheurell K., Kemnitz E., Troyanov S. I. Synthesis and X-ray structure of C2-C96(176)(CF3)18 // Mendeleev Communications. 2015. Vol. 25. No. 4. pp. 275-276.
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TY - JOUR
DO - 10.1016/j.mencom.2015.07.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.07.015
TI - Synthesis and X-ray structure of C2-C96(176)(CF3)18
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Scheurell, Kerstin
AU - Kemnitz, Erhard
AU - Troyanov, Sergey Igorevich
PY - 2015
DA - 2015/07/08
PB - Mendeleev Communications
SP - 275-276
IS - 4
VL - 25
ER -
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@article{2015_Tamm,
author = {Nadezhda Borisovna Tamm and Kerstin Scheurell and Erhard Kemnitz and Sergey Igorevich Troyanov},
title = {Synthesis and X-ray structure of C2-C96(176)(CF3)18},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.07.015},
number = {4},
pages = {275--276},
doi = {10.1016/j.mencom.2015.07.015}
}
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Tamm, Nadezhda Borisovna, et al. “Synthesis and X-ray structure of C2-C96(176)(CF3)18.” Mendeleev Communications, vol. 25, no. 4, Jul. 2015, pp. 275-276. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.07.015.

Abstract

C2-C96(176)(CF3)18 was isolated by HPLC from the trifluoromethylation products of a mixture of C94 and C96 fullerenes and its structure was determined by single crystal X-ray diffraction. The trifluoromethylation pattern is characterized by the additions in edge-sharing para C6(CF3)2 hexagons and the presence of stabilizing benzenoid rings and isolated C=C bonds on the fullerene cage.

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