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Spin propagation through the C–C and C–H bonds

Natalia Anatol'evna Chumakova 1
Natalia Anatol'evna Chumakova
, 
Anatolii Leonidovich Buchachenko 2, 3
Anatolii Leonidovich Buchachenko
10.1016/j.mencom.2015.07.010
Published 2015-07-08
Communication , Volume 25, Issue 4, 264-266
2
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Chumakova N. A., Buchachenko A. L. Spin propagation through the C–C and C–H bonds // Mendeleev Communications. 2015. Vol. 25. No. 4. pp. 264-266.
GOST all authors (up to 50) Copy
Chumakova N. A., Buchachenko A. L. Spin propagation through the C–C and C–H bonds // Mendeleev Communications. 2015. Vol. 25. No. 4. pp. 264-266.
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TY - JOUR
DO - 10.1016/j.mencom.2015.07.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.07.010
TI - Spin propagation through the C–C and C–H bonds
T2 - Mendeleev Communications
AU - Chumakova, Natalia Anatol'evna
AU - Buchachenko, Anatolii Leonidovich
PY - 2015
DA - 2015/07/08
PB - Mendeleev Communications
SP - 264-266
IS - 4
VL - 25
ER -
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@article{2015_Chumakova,
author = {Natalia Anatol'evna Chumakova and Anatolii Leonidovich Buchachenko},
title = {Spin propagation through the C–C and C–H bonds},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.07.010},
number = {4},
pages = {264--266},
doi = {10.1016/j.mencom.2015.07.010}
}
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Chumakova, Natalia Anatol'evna, and Anatolii Leonidovich Buchachenko. “Spin propagation through the C–C and C–H bonds.” Mendeleev Communications, vol. 25, no. 4, Jul. 2015, pp. 264-266. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.07.010.

Abstract

The signs of spin density on the carbon atoms and protons attached to them in nitroxides (nitroxyl radicals) with fixed geometry strictly alternate demonstrating unambiguously that spin propagation along the carbon chains of saturated C–C bonds occurs by a mechanism of spin polarization. Spin densities, both calculated and measured by NMR spectroscopy, exhibit convincing agreement both in signs and magnitudes.

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