Home / Publications / Interaction of phosphorus trichloride with triethylamine

Interaction of phosphorus trichloride with triethylamine

Alexander Nikolaevich Kornev 1
Alexander Nikolaevich Kornev
, 
Nataliya Vadimovna Zolotareva 1
Nataliya Vadimovna Zolotareva
, 
Vyacheslav Victorovich Sushev 1
Vyacheslav Victorovich Sushev
, 
Anton Vladimirovich Cherkasov 1
Anton Vladimirovich Cherkasov
, 
Gleb Arsent'evich Abakumov 1, 2
Gleb Arsent'evich Abakumov
10.1016/j.mencom.2015.05.028
Published 2015-04-28
Communication , Volume 25, Issue 3, 236-238
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kornev A. N. et al. Interaction of phosphorus trichloride with triethylamine // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 236-238.
GOST all authors (up to 50) Copy
Kornev A. N., Zolotareva N. V., Sushev V. V., Cherkasov A. V., Abakumov G. A. Interaction of phosphorus trichloride with triethylamine // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 236-238.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2015.05.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.028
TI - Interaction of phosphorus trichloride with triethylamine
T2 - Mendeleev Communications
AU - Kornev, Alexander Nikolaevich
AU - Zolotareva, Nataliya Vadimovna
AU - Sushev, Vyacheslav Victorovich
AU - Cherkasov, Anton Vladimirovich
AU - Abakumov, Gleb Arsent'evich
PY - 2015
DA - 2015/04/28
PB - Mendeleev Communications
SP - 236-238
IS - 3
VL - 25
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Kornev,
author = {Alexander Nikolaevich Kornev and Nataliya Vadimovna Zolotareva and Vyacheslav Victorovich Sushev and Anton Vladimirovich Cherkasov and Gleb Arsent'evich Abakumov},
title = {Interaction of phosphorus trichloride with triethylamine},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.028},
number = {3},
pages = {236--238},
doi = {10.1016/j.mencom.2015.05.028}
}
MLA
Cite this
MLA Copy
Kornev, Alexander Nikolaevich, et al. “Interaction of phosphorus trichloride with triethylamine.” Mendeleev Communications, vol. 25, no. 3, Apr. 2015, pp. 236-238. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.028.

Abstract

Heating of trichlorophosphine with triethylamine in acetonitrile (4h at 80°C) affords 2,2-bis(dichlorophosphino)-N,N-diethylethenamine in 38% yield and oligomeric product containing 60.5% of phosphorus.

References

1.
10.1016/j.mencom.2015.05.028_bib0005
Corbridge
Phosphorus: An Outline of its Chemistry, Biochemistry and Technology, 1980
2.
Suggestion of a “Twist” Mechanism in the Oligomerisation of a Dimeric Phospha(III)zane: Insights into the Selection of Adamantoid and Macrocyclic Alternatives
Bashall A., Doyle E.L., García F., Lawson G.T., Linton D.J., Moncrieff D., McPartlin M., Woods A.D., Wright D.S.
Chemistry - A European Journal, 2002
3.
10.1016/j.mencom.2015.05.028_bib0015
Romanenko
Zh. Obshch. Khim., 1991
4.
10.1016/j.mencom.2015.05.028_bib0020
Bourdieu
Elem., 1987
7.
Donor-Acceptor Complexes between Organoamines and Phosphorus Tribromide
Müller G., Brand J., Jetter S.E.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2001
9.
The Intramolecular Rearrangement of Phosphinohydrazides [R′2P–NR–NR–M] → [RN═PR′2–NR–M]: General Rules and Exceptions. Transformations of Bulky Phosphinohydrazines (R–NH–N(PPh2)2, R = tBu, Ph2P)
Kornev A.N., Sushev V.V., Panova Y.S., Belina N.V., Lukoyanova O.V., Fukin G.K., Ketkov S.Y., Abakumov G.A., Lönnecke P., Hey-Hawkins E.
Inorganic Chemistry, 2011
10.
G. M. Sheldrick, SHELXTL v. 6.12, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA, 2000.
11.
G. M. Sheldrick, SADABS v. 2012/1, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin, USA, 2012.
12.
Pnicogen Bonds: A New Molecular Linker?
Zahn S., Frank R., Hey‐Hawkins E., Kirchner B.
Chemistry - A European Journal, 2011
13.
Chlorophosphonation of Alkanenitrile
OKAMOTO Y., ITO T., SAKURAI H.
Journal of Japan Oil Chemists Society, 1973