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Heteroligand nickel siloxane with 4-vinylbenzyl substituents

Alexander Aleksandrovich Korlyukov
Marina A Eskova 1
Marina A Eskova
Igor Mikhailovich Tkachenko 2
Igor Mikhailovich Tkachenko
Yuriy Nikolaevich Kononevich 1
Yuriy Nikolaevich Kononevich
Olga Ivanovna Shchegolikhina 1
Olga Ivanovna Shchegolikhina
2 Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
Published 2015-04-28
CommunicationVolume 25, Issue 3, 226-228
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Korlyukov A. A. et al. Heteroligand nickel siloxane with 4-vinylbenzyl substituents // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 226-228.
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Korlyukov A. A., Eskova M. A., Tkachenko I. M., Kononevich Y. N., Shchegolikhina O. I., Muzafarov A. M. Heteroligand nickel siloxane with 4-vinylbenzyl substituents // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 226-228.
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TY - JOUR
DO - 10.1016/j.mencom.2015.05.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.024
TI - Heteroligand nickel siloxane with 4-vinylbenzyl substituents
T2 - Mendeleev Communications
AU - Korlyukov, Alexander Aleksandrovich
AU - Eskova, Marina A
AU - Tkachenko, Igor Mikhailovich
AU - Kononevich, Yuriy Nikolaevich
AU - Shchegolikhina, Olga Ivanovna
AU - Muzafarov, Aziz Mansurovich
PY - 2015
DA - 2015/04/28
PB - Mendeleev Communications
SP - 226-228
IS - 3
VL - 25
ER -
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@article{2015_Korlyukov,
author = {Alexander Aleksandrovich Korlyukov and Marina A Eskova and Igor Mikhailovich Tkachenko and Yuriy Nikolaevich Kononevich and Olga Ivanovna Shchegolikhina and Aziz Mansurovich Muzafarov},
title = {Heteroligand nickel siloxane with 4-vinylbenzyl substituents},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.024},
number = {3},
pages = {226--228},
doi = {10.1016/j.mencom.2015.05.024}
}
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Korlyukov, Alexander Aleksandrovich, et al. “Heteroligand nickel siloxane with 4-vinylbenzyl substituents.” Mendeleev Communications, vol. 25, no. 3, Apr. 2015, pp. 226-228. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.024.

Abstract

A new polyherdal nickel siloxane was synthesized by the hydrolysis of triethoxy(4-vinylbenzyl)silane in the presence of NaOH and the subsequent interaction with [Ni(NH3)6]Cl2. The nickel siloxane has a dimeric structure that consists of two polyhedral sandwiched pentanuclear nickel siloxane units linked by very strong O–H···O bonds into infinite chains in a crystal.

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