Home / Publications / Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters

Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters

Alexandr Nikolaevich Subbotin 1
Alexandr Nikolaevich Subbotin
Irina Rudol'fovna Subbotina 1
Irina Rudol'fovna Subbotina
Evgeny Zinov'evich Golosman 2
Evgeny Zinov'evich Golosman
2 Novomoskovsk Institute of Nitrogen Industry, Novomoskovsk, Tula Region, Russian Federation
Published 2015-04-28
CommunicationVolume 25, Issue 3, 216-218
9
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Subbotin A. N., Subbotina I. R., Golosman E. Z. Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 216-218.
GOST all authors (up to 50) Copy
Subbotin A. N., Subbotina I. R., Golosman E. Z. Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 216-218.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2015.05.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.020
TI - Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters
T2 - Mendeleev Communications
AU - Subbotin, Alexandr Nikolaevich
AU - Subbotina, Irina Rudol'fovna
AU - Golosman, Evgeny Zinov'evich
PY - 2015
DA - 2015/04/28
PB - Mendeleev Communications
SP - 216-218
IS - 3
VL - 25
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Subbotin,
author = {Alexandr Nikolaevich Subbotin and Irina Rudol'fovna Subbotina and Evgeny Zinov'evich Golosman},
title = {Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.020},
number = {3},
pages = {216--218},
doi = {10.1016/j.mencom.2015.05.020}
}
MLA
Cite this
MLA Copy
Subbotin, Alexandr Nikolaevich, et al. “Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters.” Mendeleev Communications, vol. 25, no. 3, Apr. 2015, pp. 216-218. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.020.

Abstract

Hysteresis in hydrogenation reactions has been found for the first time. A concept of the local overheating of active nanoparticles in a catalyst due to hindered reaction heat removal has been suggested to explain the origins of the appearance of a hysteresis loop.

References

1.
G. S. Yablonskii, 1V. I. Bykov, M.G. Slin’ko and Yu. I. Kuznetsov, Dokl. Akad. Nauk SSSR, 1976, 229, 917.(in Russian).
2.
Study of CO oxidation on the (111) face of nickel during Ni−NiO phase transition
Kalinkin A.V., Boreskov G.K., Savchenko V.I., Dadayan K.A.
Reaction Kinetics and Catalysis Letters, 1980
3.
A. H. Salanov and V. I. Savchenko, Kinet. Katal., 1985, 26, 1136 (in Russian).
5.
I. I. Mikhalenko, Dr. Sci. Thesis, Moscow, RUDN, 1999, p. 451.(in Russian).
6.
I. V. Krylova, Tezisy dokladov III seminara po teoreticheskim problemam kataliza ‘Kataliticheskie prevrashcheniya odnouglerodnykh molekul’ (Abstracts of III Workshop on Theoretical Problems in Catalysis ‘Catalytic Transformations of One-carbon Molecules’), Chernogolovka, 1998, p. 104.(in Russian).
8.
Mathematical Models of Catalytic Combustors
Groppi G., Tronconi E., Forzatti P.
Catalysis Reviews - Science and Engineering, 1999
9.
Methane oxidation hysteresis over Pt/Al2O3
Amin A., Abedi A., Hayes R., Votsmeier M., Epling W.
Applied Catalysis A: General, 2014
10.
Taking advantage of hysteresis in methane partial oxidation over Pt on honeycomb monolith
Dalle Nogare D., Salemi S., Biasi P., Canu P.
Chemical Engineering Science, 2011
11.
10.1016/j.mencom.2015.05.020_bib0055
Chen
J. Power Sources, 2009
13.
10.1016/j.mencom.2015.05.020_bib0065
2000
14.
10.1016/j.mencom.2015.05.020_bib0070
Yakerson
Zh. Fiz. Khim., 2000
15.
Preparation of catalyst carriers on the basis of alumina supported on metallic gauzes
Vorob’eva M.P., Greish A.A., Ivanov A.V., Kustov L.M.
Applied Catalysis A: General, 2000
16.
10.1016/j.mencom.2015.05.020_bib0080
Parmon
Kinet. Katal., 1996
17.
10.1016/j.mencom.2015.05.020_bib0085
Carslaw
Conduction of Heat in Solids, 1959
18.
Concentration hysteresis in methane oxidation on nanosized platinum particles
Pakharukov I.Y., Bekk I.E., Matrosova M.M., Bukhtiyarov V.I., Parmon V.N.
Doklady Physical Chemistry, 2011
19.
A reactive phase diagram of CO oxidation on Pd(110): Steady and oscillatory states
Ehsasi M., Berdau M., Rebitzki T., Charlé K.‐., Christmann K., Block J.H.
Journal of Chemical Physics, 1993
20.
Macroscopic and mesoscopic characterization of a bistable reaction system: CO oxidation on Pt(111) surface
Berdau M., Yelenin G.G., Karpowicz A., Ehsasi M., Christmann K., Block J.H.
Journal of Chemical Physics, 1999
21.
10.1016/j.mencom.2015.05.020_bib0105
Buendía
J. Chem. Phys., 2009