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Unexpected formation of (trinitromethyl)pyrazines

Igor L Yudin 1
Igor L Yudin
, 
Nadezhda Vladimirovna Palysaeva 1
Nadezhda Vladimirovna Palysaeva
, 
Boris Borisovich Averkiev 2
Boris Borisovich Averkiev
, 
Aleksei Borisovich Sheremetev 1
Aleksei Borisovich Sheremetev
10.1016/j.mencom.2015.05.011
Published 2015-04-28
Communication , Volume 25, Issue 3, 193-195
5
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Yudin I. L. et al. Unexpected formation of (trinitromethyl)pyrazines // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 193-195.
GOST all authors (up to 50) Copy
Yudin I. L., Palysaeva N. V., Averkiev B. B., Sheremetev A. B. Unexpected formation of (trinitromethyl)pyrazines // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 193-195.
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TY - JOUR
DO - 10.1016/j.mencom.2015.05.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.011
TI - Unexpected formation of (trinitromethyl)pyrazines
T2 - Mendeleev Communications
AU - Yudin, Igor L
AU - Palysaeva, Nadezhda Vladimirovna
AU - Averkiev, Boris Borisovich
AU - Sheremetev, Aleksei Borisovich
PY - 2015
DA - 2015/04/28
PB - Mendeleev Communications
SP - 193-195
IS - 3
VL - 25
ER -
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@article{2015_Yudin,
author = {Igor L Yudin and Nadezhda Vladimirovna Palysaeva and Boris Borisovich Averkiev and Aleksei Borisovich Sheremetev},
title = {Unexpected formation of (trinitromethyl)pyrazines},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.011},
number = {3},
pages = {193--195},
doi = {10.1016/j.mencom.2015.05.011}
}
MLA
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MLA Copy
Yudin, Igor L., et al. “Unexpected formation of (trinitromethyl)pyrazines.” Mendeleev Communications, vol. 25, no. 3, Apr. 2015, pp. 193-195. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.011.

Abstract

Treatment of 2-alkoxy-3-methylpyrazines with HNO3 /H2SO4 induces an unusual reaction accompanied by the methyl group nitration with the formation of (trinitromethyl)pyrazines, a structural motif previously unknown in diazine family.

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