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1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation

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Akira Sekiguchi 1
Akira Sekiguchi
10.1016/j.mencom.2015.05.001
Published 2015-04-28
Focus article , Volume 25, Issue 3, 161-167
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Lee V. Y., Sekiguchi A. 1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 161-167.
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Lee V. Y., Sekiguchi A. 1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation // Mendeleev Communications. 2015. Vol. 25. No. 3. pp. 161-167.
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TY - JOUR
DO - 10.1016/j.mencom.2015.05.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.001
TI - 1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation
T2 - Mendeleev Communications
AU - Lee, Vladimir Yaroslavovich
AU - Sekiguchi, Akira
PY - 2015
DA - 2015/04/28
PB - Mendeleev Communications
SP - 161-167
IS - 3
VL - 25
ER -
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@article{2015_Lee,
author = {Vladimir Yaroslavovich Lee and Akira Sekiguchi},
title = {1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.001},
number = {3},
pages = {161--167},
doi = {10.1016/j.mencom.2015.05.001}
}
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Lee, Vladimir Yaroslavovich, and Akira Sekiguchi. “1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation.” Mendeleev Communications, vol. 25, no. 3, Apr. 2015, pp. 161-167. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.05.001.
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Abstract

Novel main group element compounds, geminal dianionic derivatives of the heavier group 14 elements; namely, 1,1-dilithiosilanes, 1,1-dilithiogermanes and 1,1-dilithiostannanes (and closely related derivatives of the cyclopentadiene-1,1-diide and cyclobutadiene dianion), are the focus of the present review. The synthetic strategies for their preparation, structural features, and synthetic applications are discussed.

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