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Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles

Dmitrii Andreevich Shabalin 1
Dmitrii Andreevich Shabalin
, 
Marina Yu Dvorko 1
Marina Yu Dvorko
, 
Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Nadezhda Il'inichna Protsuk 1
Nadezhda Il'inichna Protsuk
, 
Igor Alekseevich Ushakov 1
Igor Alekseevich Ushakov
, 
Albina Ivanovna Mikhaleva 1
Albina Ivanovna Mikhaleva
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2015.03.017
Published 2015-03-06
Communication , Volume 25, Issue 2, 129-130
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Shabalin D. A. et al. Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 129-130.
GOST all authors (up to 50) Copy
Shabalin D. A., Dvorko M. Yu., Schmidt E. Y., Protsuk N. I., Ushakov I. A., Mikhaleva A. I., Trofimov B. A. Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 129-130.
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TY - JOUR
DO - 10.1016/j.mencom.2015.03.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.017
TI - Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles
T2 - Mendeleev Communications
AU - Shabalin, Dmitrii Andreevich
AU - Dvorko, Marina Yu
AU - Schmidt, Elena Yur'evna
AU - Protsuk, Nadezhda Il'inichna
AU - Ushakov, Igor Alekseevich
AU - Mikhaleva, Albina Ivanovna
AU - Trofimov, Boris Aleksandrovich
PY - 2015
DA - 2015/03/06
PB - Mendeleev Communications
SP - 129-130
IS - 2
VL - 25
ER -
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@article{2015_Shabalin,
author = {Dmitrii Andreevich Shabalin and Marina Yu Dvorko and Elena Yur'evna Schmidt and Nadezhda Il'inichna Protsuk and Igor Alekseevich Ushakov and Albina Ivanovna Mikhaleva and Boris Aleksandrovich Trofimov},
title = {Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.017},
number = {2},
pages = {129--130},
doi = {10.1016/j.mencom.2015.03.017}
}
MLA
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Shabalin, Dmitrii Andreevich, et al. “Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 129-130. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.017.

Abstract

Cyclohexyl phenyl and cyclohexyl (2-thienyl) ketoximes react with acetylene under pressure in the two-phase KOH/DMSO/n-hexane system at 70°C to afford the corresponding spirocyclic 3H-pyrroles, 1-(het)aryl-2-azaspiro[4.5]deca-1,3-dienes, in 18–19% yields.

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