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Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids

Margarita Alekseevna Epishina 1
Margarita Alekseevna Epishina
, 
Alexander Sergeyevich Kulikov 1
Alexander Sergeyevich Kulikov
, 
Nikolai V Ignat'ev 2
Nikolai V Ignat'ev
, 
Michael Schulte 2
Michael Schulte
, 
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
2 Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany
10.1016/j.mencom.2015.03.016
Published 2015-03-06
Communication , Volume 25, Issue 2, 126-128
7
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Epishina M. A. et al. Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 126-128.
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Epishina M. A., Kulikov A. S., Ignat'ev N. V., Schulte M., Makhova N. N. Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 126-128.
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TY - JOUR
DO - 10.1016/j.mencom.2015.03.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.016
TI - Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids
T2 - Mendeleev Communications
AU - Epishina, Margarita Alekseevna
AU - Kulikov, Alexander Sergeyevich
AU - Ignat'ev, Nikolai V
AU - Schulte, Michael
AU - Makhova, Nina Nikolaevna
PY - 2015
DA - 2015/03/06
PB - Mendeleev Communications
SP - 126-128
IS - 2
VL - 25
ER -
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@article{2015_Epishina,
author = {Margarita Alekseevna Epishina and Alexander Sergeyevich Kulikov and Nikolai V Ignat'ev and Michael Schulte and Nina Nikolaevna Makhova},
title = {Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.016},
number = {2},
pages = {126--128},
doi = {10.1016/j.mencom.2015.03.016}
}
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Epishina, Margarita Alekseevna, et al. “Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 126-128. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.016.

Abstract

The Chapman rearrangement of aryl N-arylbenzimidates to tertiary acyclic amides is accelerated in ionic liquids and proceeds at lower temperatures as 120–190°C.

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