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Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions

Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
, 
Lyudmila Vyacheslavovna Afanas'eva 1
Lyudmila Vyacheslavovna Afanas'eva
, 
Irina Mikhailovna Churilova 1
Irina Mikhailovna Churilova
, 
Oleg Ivanovich Artyushin 1
Oleg Ivanovich Artyushin
, 
Nikolai Dmitrievich Kagramanov 1
Nikolai Dmitrievich Kagramanov
10.1016/j.mencom.2015.03.015
Published 2015-03-06
Communication , Volume 25, Issue 2, 124-125
6
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Akhrem I. S. et al. Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 124-125.
GOST all authors (up to 50) Copy
Akhrem I. S., Afanas'eva L. V., Churilova I. M., Artyushin O. I., Kagramanov N. D. Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 124-125.
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TY - JOUR
DO - 10.1016/j.mencom.2015.03.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.015
TI - Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions
T2 - Mendeleev Communications
AU - Akhrem, Irena Sergeevna
AU - Afanas'eva, Lyudmila Vyacheslavovna
AU - Churilova, Irina Mikhailovna
AU - Artyushin, Oleg Ivanovich
AU - Kagramanov, Nikolai Dmitrievich
PY - 2015
DA - 2015/03/06
PB - Mendeleev Communications
SP - 124-125
IS - 2
VL - 25
ER -
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@article{2015_Akhrem,
author = {Irena Sergeevna Akhrem and Lyudmila Vyacheslavovna Afanas'eva and Irina Mikhailovna Churilova and Oleg Ivanovich Artyushin and Nikolai Dmitrievich Kagramanov},
title = {Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.015},
number = {2},
pages = {124--125},
doi = {10.1016/j.mencom.2015.03.015}
}
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Akhrem, Irena Sergeevna, et al. “Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 124-125. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.015.

Abstract

Treatment of nonanamides C8H17C(O)NR2 (R = H or Et) with superelectrophilic complex CBr4·2AlBr3 under CO atmosphere followed by quenching with nucleophiles NuH cleanly gives 7-methyl-7-(Nu-carbonyl)octanamide bifunctional derivatives.

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