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Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives

Pavel Arsenyan 1
Pavel Arsenyan
, 
Edgars Paegle 1
Edgars Paegle
, 
Sergey Belyakov 1
Sergey Belyakov
10.1016/j.mencom.2015.03.013
Published 2015-03-06
Communication , Volume 25, Issue 2, 119-120
4
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Arsenyan P., Paegle E., Belyakov S. Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 119-120.
GOST all authors (up to 50) Copy
Arsenyan P., Paegle E., Belyakov S. Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 119-120.
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TY - JOUR
DO - 10.1016/j.mencom.2015.03.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.013
TI - Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives
T2 - Mendeleev Communications
AU - Arsenyan, Pavel
AU - Paegle, Edgars
AU - Belyakov, Sergey
PY - 2015
DA - 2015/03/06
PB - Mendeleev Communications
SP - 119-120
IS - 2
VL - 25
ER -
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@article{2015_Arsenyan,
author = {Pavel Arsenyan and Edgars Paegle and Sergey Belyakov},
title = {Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.013},
number = {2},
pages = {119--120},
doi = {10.1016/j.mencom.2015.03.013}
}
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Arsenyan, Pavel, et al. “Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 119-120. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.013.

Abstract

Microwave-assisted palladium-catalyzed cyanation of 3-bromo-2-(1-hydroxyalkyl)benzo[b]selenophene affords 3-cyano derivatives. Raising the temperature promotes formation of 2-(1-alkenyl)-3-carbamoyl isomers through intramolecular transfer of water.

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