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Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+

Dmitry Victorovich Muratov 1
Dmitry Victorovich Muratov
, 
Alexander Sergeyevich Romanov 1
Alexander Sergeyevich Romanov
, 
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
10.1016/j.mencom.2015.03.009
Published 2015-03-06
Communication , Volume 25, Issue 2, 109-110
2
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Muratov D. V., Romanov A. S., Kudinov A. R. Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+ // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 109-110.
GOST all authors (up to 50) Copy
Muratov D. V., Romanov A. S., Kudinov A. R. Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+ // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 109-110.
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TY - JOUR
DO - 10.1016/j.mencom.2015.03.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.009
TI - Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+
T2 - Mendeleev Communications
AU - Muratov, Dmitry Victorovich
AU - Romanov, Alexander Sergeyevich
AU - Kudinov, Alexander Rudolfovich
PY - 2015
DA - 2015/03/06
PB - Mendeleev Communications
SP - 109-110
IS - 2
VL - 25
ER -
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@article{2015_Muratov,
author = {Dmitry Victorovich Muratov and Alexander Sergeyevich Romanov and Alexander Rudolfovich Kudinov},
title = {Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.009},
number = {2},
pages = {109--110},
doi = {10.1016/j.mencom.2015.03.009}
}
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Muratov, Dmitry Victorovich, et al. “Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 109-110. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.009.

Abstract

The cationic complex [Cp*Ru(C5Me4CH2)]+ reacts with Et3N primarily giving the ammonium salt [Cp*Ru(C5Me4CH2NEt3)]+. The prolonged standing of the reaction mixture results in the formation of the ether Cp*Ru(C5Me4CH2OCH2C5Me4)RuCp*. The reaction of [Cp*Ru(C5Me4CH2)]+ with PhNEt2 leads to the electrophilic aromatic substitution product [Cp*Ru(C5Me4CH2C6H4NHEt2)]+.

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