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Phosphorescence of a ruthenium(II) hydride-carbonyl complex with 3-hydroxy-2-quinoxalinecarboxylic acid as a co-ligand

Jan Grzegorz Malecki 1
Jan Grzegorz Malecki
, 
Anna Maron 1
Anna Maron
, 
Joachim Kusz 2
Joachim Kusz
10.1016/j.mencom.2015.03.007
Published 2015-03-06
Communication , Volume 25, Issue 2, 103-105
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Malecki J. G., Maron A., Kusz J. Phosphorescence of a ruthenium(II) hydride-carbonyl complex with 3-hydroxy-2-quinoxalinecarboxylic acid as a co-ligand // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 103-105.
GOST all authors (up to 50) Copy
Malecki J. G., Maron A., Kusz J. Phosphorescence of a ruthenium(II) hydride-carbonyl complex with 3-hydroxy-2-quinoxalinecarboxylic acid as a co-ligand // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 103-105.
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TY - JOUR
DO - 10.1016/j.mencom.2015.03.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.007
TI - Phosphorescence of a ruthenium(II) hydride-carbonyl complex with 3-hydroxy-2-quinoxalinecarboxylic acid as a co-ligand
T2 - Mendeleev Communications
AU - Malecki, Jan Grzegorz
AU - Maron, Anna
AU - Kusz, Joachim
PY - 2015
DA - 2015/03/06
PB - Mendeleev Communications
SP - 103-105
IS - 2
VL - 25
ER -
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@article{2015_Malecki,
author = {Jan Grzegorz Malecki and Anna Maron and Joachim Kusz},
title = {Phosphorescence of a ruthenium(II) hydride-carbonyl complex with 3-hydroxy-2-quinoxalinecarboxylic acid as a co-ligand},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.007},
number = {2},
pages = {103--105},
doi = {10.1016/j.mencom.2015.03.007}
}
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Malecki, Jan Grzegorz, et al. “Phosphorescence of a ruthenium(II) hydride-carbonyl complex with 3-hydroxy-2-quinoxalinecarboxylic acid as a co-ligand.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 103-105. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.03.007.

Abstract

The [RuH(CO)(hqxc)(PPh3)2] complex, where hqxc is 3-hydroxy-2-quinoxalinecarboxylate, exhibits strong phosphorescence (quantum yield F = 0.0078) in the solid state giving rise to a significantly Stokes-shifted spectrum (excitation at 484nm and emission at 687nm); the lifetime of 6.5μs is very long compared with 0.68ns measured for the free hqxc ligand.

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