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Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set

Ali Iskhakovich Uraev 1
Ali Iskhakovich Uraev
Leonid Dmitrievich Popov 1
Leonid Dmitrievich Popov
Sergei Ivanovich Levchenkov 2
Sergei Ivanovich Levchenkov
Igor Nikolaevich Shcherbakov 1
Igor Nikolaevich Shcherbakov
Kirill Yu Suponitsky 3
Kirill Yu Suponitsky
Dmitrii Aleksandrovich Garnovskii 2
Dmitrii Aleksandrovich Garnovskii
Vladimir Viktorovich Lukov 1
Vladimir Viktorovich Lukov
Victor Aleksandrovich Kogan 1
Victor Aleksandrovich Kogan
Published 2014-12-26
CommunicationVolume 25, Issue 1, 62-64
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Uraev A. I. et al. Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 62-64.
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Uraev A. I., Popov L. D., Levchenkov S. I., Shcherbakov I. N., Suponitsky K. Yu., Garnovskii D. A., Lukov V. V., Kogan V. A. Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 62-64.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.023
TI - Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set
T2 - Mendeleev Communications
AU - Uraev, Ali Iskhakovich
AU - Popov, Leonid Dmitrievich
AU - Levchenkov, Sergei Ivanovich
AU - Shcherbakov, Igor Nikolaevich
AU - Suponitsky, Kirill Yu
AU - Garnovskii, Dmitrii Aleksandrovich
AU - Lukov, Vladimir Viktorovich
AU - Kogan, Victor Aleksandrovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 62-64
IS - 1
VL - 25
ER -
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@article{2014_Uraev,
author = {Ali Iskhakovich Uraev and Leonid Dmitrievich Popov and Sergei Ivanovich Levchenkov and Igor Nikolaevich Shcherbakov and Kirill Yu Suponitsky and Dmitrii Aleksandrovich Garnovskii and Vladimir Viktorovich Lukov and Victor Aleksandrovich Kogan},
title = {Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.023},
number = {1},
pages = {62--64},
doi = {10.1016/j.mencom.2015.01.023}
}
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Uraev, Ali Iskhakovich, et al. “Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 62-64. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.023.

Abstract

A carbonate-bridged tetranuclear CuII complex of the general formula [(Cu2L)2CO3]·2MeCN (L is triply deprotonated Schiff base condensation product of 1,3-diaminopropan-2-ol and 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole) has been obtained by the slow crystallization of dinuclear complex [(Cu2L)CCl3COO] from acetonitrile and studied by X-ray diffraction and low-temperature magnetic measurements.

References

1.
Bimetallic dioxygen complexes derived from ‘end-off’ compartmental ligands
Suzuki M., Furutachi H., Ōkawa H.
Coordination Chemistry Reviews, 2000
2.
The challenge of cyclic and acyclic schiff bases and related derivatives
Vigato P.A., Tamburini S.
Coordination Chemistry Reviews, 2004
3.
Magnetic exchange in Bi- and polynuclear complexes of transition metals with hydrazones and azomethines
Kogan V.A., Lukov V.V., Shcherbakov I.N.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2010
6.
Triggering the Sign of Magnetic Exchange Coupling in a Dinuclear Copper(II) Complex by Solvent Molecule Coordination
Shcherbakov I.N., Levchenkov S.I., Tupolova Y.P., Popov L.D., Vlasenko V.G., Zubavichus Y.V., Lukov V.V., Kogan V.A.
European Journal of Inorganic Chemistry, 2013
9.
Tetranuclear Copper(II) Complex with N,N′-bis(2-N-Tosylaminobenzylidene)-1,3-Diaminopropan-2-ol: Crystal structure and magnetic properties
Popov L.D., Levchenkov S.I., Shcherbakov I.N., Suponitskii K.Y., Burlov A.S., Beloborodov S.S., Lukov V.V., Kogan V.A.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2013
11.
Density functional study of magnetostructural correlations in cubane complexes containing the Cu4O4core
Tercero J., Ruiz E., Alvarez S., Rodríguez-Fortea A., Alemany P.
Journal of Materials Chemistry A, 2006
13.
Chemistry and Physics of Supramolecular Magnetic Materials
14.
Structural and Functional Aspects of Metal Sites in Biology
Holm R.H., Kennepohl P., Solomon E.I.
Chemical Reviews, 1996
15.
Recent advances in understanding blue copper proteins
Solomon E.I., Hadt R.G.
Coordination Chemistry Reviews, 2011
16.
Transition metal complexes of quadridentate pyrazolo-based ligands with two thiolato and two imine donor atoms
Hennig L., Kirmse R., Hammerich O., Larsen S., Frydendahl H., Toftlund H., Becher J.
Inorganica Chimica Acta, 1995
18.
10.1016/j.mencom.2015.01.023_bib0090
Kahn
Molecular Magnetism, 1993
19.
Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.
Appel A.M., Bercaw J.E., Bocarsly A.B., Dobbek H., DuBois D.L., Dupuis M., Ferry J.G., Fujita E., Hille R., Kenis P.J., Kerfeld C.A., Morris R.H., Peden C.H., Portis A.R., Ragsdale S.W., et. al.
Chemical Reviews, 2013
20.
Unexpected Ferromagnetic Interaction in a New Tetranuclear Copper(II) Complex:  Synthesis, Crystal Structure, Magnetic Properties, and Theoretical Studies
Fondo M., García-Deibe A.M., Corbella M., Ruiz E., Tercero J., Sanmartín J., Bermejo M.R.
Inorganic Chemistry, 2005
22.
A new unique tetranuclear Cu(II) compound with double bridging thiocyanate anions: Synthesis, X-ray structure and magnetism of [Cu4(μ1,3-NCS)6(dpyam)4(O2CH)2(H2O)2] (dpyam=di-2-pyridylamine)