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Facile reaction of bis(tri-n-butyltin) oxide with silica gel

Alexey Aleksandrovich Grachev 1
Alexey Aleksandrovich Grachev
, 
Margarita Aleksandrovna Lapitskaya 1
Margarita Aleksandrovna Lapitskaya
, 
Ljudmila Leonidovna Vasiljeva 1
Ljudmila Leonidovna Vasiljeva
, 
Kazimir Konstantinovich Pivnitsky 1
Kazimir Konstantinovich Pivnitsky
10.1016/j.mencom.2015.01.019
Published 2014-12-26
Communication , Volume 25, Issue 1, 51-53
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Grachev A. A. et al. Facile reaction of bis(tri-n-butyltin) oxide with silica gel // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 51-53.
GOST all authors (up to 50) Copy
Grachev A. A., Lapitskaya M. A., Vasiljeva L. L., Pivnitsky K. K. Facile reaction of bis(tri-n-butyltin) oxide with silica gel // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 51-53.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.019
TI - Facile reaction of bis(tri-n-butyltin) oxide with silica gel
T2 - Mendeleev Communications
AU - Grachev, Alexey Aleksandrovich
AU - Lapitskaya, Margarita Aleksandrovna
AU - Vasiljeva, Ljudmila Leonidovna
AU - Pivnitsky, Kazimir Konstantinovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 51-53
IS - 1
VL - 25
ER -
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@article{2014_Grachev,
author = {Alexey Aleksandrovich Grachev and Margarita Aleksandrovna Lapitskaya and Ljudmila Leonidovna Vasiljeva and Kazimir Konstantinovich Pivnitsky},
title = {Facile reaction of bis(tri-n-butyltin) oxide with silica gel},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.019},
number = {1},
pages = {51--53},
doi = {10.1016/j.mencom.2015.01.019}
}
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Grachev, Alexey Aleksandrovich, et al. “Facile reaction of bis(tri-n-butyltin) oxide with silica gel.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 51-53. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.019.

Abstract

Bis(tri-n-butyltin) oxide quickly reacts with chromatographic silica gel even when a solution of this oxide is filtered through silica gel, which results in stannylation of a fraction of the surface hydroxyl groups of silica gel to give n-Bu3SnOSi° moieties. The calculated surface density of these moieties, 0.85 Sn groups per nm2, corresponds to complete coverage of silica gel surface with n-Bu groups.

References

2.
Synthetic Uses of R3MH (M = Ge, Sn, Pb)
Carland M.W., Schiesser C.H.
Chemistry of Functional Groups, 2002
3.
Biological Activity of Organotin and Organolead Compounds
Lukevics E., Pudova O.
Chemistry of Functional Groups, 2002
4.
Encapsulation of organotin compounds in metal acetate glasses
Duffy J.A., Harston P., Wardell J.L., Smith P.J.
Applied Organometallic Chemistry, 1990
5.
Reactions of organostannanes with silica, .gamma.-alumina, and silica-alumina
Ballivet-Tkatchenko D., dos Santos J.H., Malisova M.
Langmuir, 1993
6.
Surface organometallic chemistry of tin: reactivity of tetraalkyltin complexes and tributyltin hydride toward silica
Nedez C., Theolier A., Lefebvre F., Choplin A., Basset J.M., Joly J.F.
Journal of the American Chemical Society, 1993
8.
Surface Organometallic Chemistry of Tin: Reaction of Hydridotris(butyl)tin with the Surfaces of Partially Dehydroxylated Aluminas
Nedez C., Lefebvre F., Choplin A., Niccolai G.P., Basset J., Benazzi E.
Journal of the American Chemical Society, 1994
11.
Modern Surface Organometallic Chemistry, eds. J.-M. Basset, R. Psaro, D. Roberto and R. Ugo, Wiley-VCH, Weinheim, 2009, pp. 31, 168, 426.
13.
A reexamination of the chemisorption of trimethylaluminum on silica
Bartram M.E., Michalske T.A., Rogers J.W.
The Journal of Physical Chemistry, 1991
14.
L. T. Zhuravlev, in Colloidal Silica. Fundamental and Applications, eds. H. E. Bergna and W. O. Roberts, Taylor & Francis Group, Boca Raton, 2006, p. 262.
18.
Hydrogen bonding in adsorption on silica
Curthoys G., Davydov V.Y., Kiselev A.V., Kiselev S.A., Kuznetsov B.V.
Journal of Colloid and Interface Science, 1974
20.
Silicon-29 NMR study of silica
Leonardelli S., Facchini L., Fretigny C., Tougne P., Legrand A.P.
Journal of the American Chemical Society, 1992
23.
Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning
Maciel G.E., Sindorf D.W.
Journal of the American Chemical Society, 1980
29.
The Epoxidation of C5–C10Alkenes With Hydrogen Peroxide Catalysed by Mo Compounds in Two-phase Solvents
Kamiyama T., Inoue M., Kashiwagi H., Enomoto S.
Bulletin of the Chemical Society of Japan, 1990
31.
Scope and Mechanism of Deprotection of Carboxylic Esters by Bis(tributyltin) Oxide
Salomon C.J., Mata E.G., Mascaretti O.A.
Journal of Organic Chemistry, 1994
32.
Synthesis of Glycosylamines from Glycosyl Isothiocyanates and Bis(tributyltin) Oxide
Isac-García J., Calvo-Flores F., Hernández-Mateo F., Santoyo-González F.
European Journal of Organic Chemistry, 2001
35.
Potassium carbonate–silica: a highly effective stationary phase for the chromatographic removal of organotin impurities
Harrowven D.C., Curran D.P., Kostiuk S.L., Wallis-Guy I.L., Whiting S., Stenning K.J., Tang B., Packard E., Nanson L.
Chemical Communications, 2010
36.
Target-oriented analysis of gaseous, liquid and solid chemical systems by mass spectrometry, nuclear magnetic resonance spectroscopy and electron microscopy
Kachala V.V., Khemchyan L.L., Kashin A.S., Orlov N.V., Grachev A.A., Zalesskiy S.S., Ananikov V.P.
Russian Chemical Reviews, 2013