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Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides

, 
Alexander Viktorovich Samet 3
Alexander Viktorovich Samet
, 
Leonid Dmitrievich Konyushkin 3
Leonid Dmitrievich Konyushkin
,  , 
Vitaly Konstantinovich Belsky 4
Vitaly Konstantinovich Belsky
, 
Victor Vladimirovich Semenov 3
Victor Vladimirovich Semenov
10.1016/j.mencom.2015.01.016
Published 2014-12-26
Communication , Volume 25, Issue 1, 44-46
12
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Brel V. K. et al. Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 44-46.
GOST all authors (up to 50) Copy
Brel V. K., Samet A. V., Konyushkin L. D., Stash A. I., Belsky V. K., Semenov V. V. Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 44-46.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.016
TI - Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides
T2 - Mendeleev Communications
AU - Brel, Valery Kuzmich
AU - Samet, Alexander Viktorovich
AU - Konyushkin, Leonid Dmitrievich
AU - Stash, Adam Igarkovich
AU - Belsky, Vitaly Konstantinovich
AU - Semenov, Victor Vladimirovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 44-46
IS - 1
VL - 25
ER -
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@article{2014_Brel,
author = {Valery Kuzmich Brel and Alexander Viktorovich Samet and Leonid Dmitrievich Konyushkin and Adam Igarkovich Stash and Vitaly Konstantinovich Belsky and Victor Vladimirovich Semenov},
title = {Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.016},
number = {1},
pages = {44--46},
doi = {10.1016/j.mencom.2015.01.016}
}
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Brel, Valery Kuzmich, et al. “Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 44-46. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.016.

Abstract

Simple chiral precursors for the preparation of methylene-expanded C-nucleosides were developed, using as key steps pyrolysis of cellulose to levoglucosenone followed by hydrogenation and introduction of vinyl and ethynyl fragments to the 2-position.

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