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Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction

Margarita Alekseevna Epishina 1
Margarita Alekseevna Epishina
, 
Alexander Sergeyevich Kulikov 1
Alexander Sergeyevich Kulikov
, 
Nikolai V Ignat'ev 2
Nikolai V Ignat'ev
, 
Michael Schulte 2
Michael Schulte
, 
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
2 Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany
10.1016/j.mencom.2015.01.015
Published 2014-12-26
Communication , Volume 25, Issue 1, 41-43
9
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Epishina M. A. et al. Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 41-43.
GOST all authors (up to 50) Copy
Epishina M. A., Kulikov A. S., Ignat'ev N. V., Schulte M., Makhova N. N. Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 41-43.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.015
TI - Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction
T2 - Mendeleev Communications
AU - Epishina, Margarita Alekseevna
AU - Kulikov, Alexander Sergeyevich
AU - Ignat'ev, Nikolai V
AU - Schulte, Michael
AU - Makhova, Nina Nikolaevna
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 41-43
IS - 1
VL - 25
ER -
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@article{2014_Epishina,
author = {Margarita Alekseevna Epishina and Alexander Sergeyevich Kulikov and Nikolai V Ignat'ev and Michael Schulte and Nina Nikolaevna Makhova},
title = {Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.015},
number = {1},
pages = {41--43},
doi = {10.1016/j.mencom.2015.01.015}
}
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MLA Copy
Epishina, Margarita Alekseevna, et al. “Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 41-43. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.015.

Abstract

Conversion of 4-R-nitrobenzenes into 3-R-benzoic acids under the action of KCN in the EtOH–H2O mixture (the von Richter reaction) is significantly accelerated by ionic liquids thus allowing to extend the scope of the reaction. The finding is pioneering ionic liquid- promoted nucleophilic aromatic cine-substitution of hydrogen.

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